The effect of the substituents in the malonate anion and the solvent molecules on the structures of novel coordination polymers [Li2VO(R2mal)2]n
- Авторы: Bazhina E.S.1, Aleksandrov G.G.1, Kiskin M.A.1, Sidorov A.A.1, Eremenko I.L.1
-
Учреждения:
- N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Выпуск: Том 65, № 1 (2016)
- Страницы: 249-258
- Раздел: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/236981
- DOI: https://doi.org/10.1007/s11172-016-1293-3
- ID: 236981
Цитировать
Аннотация
Reactions of vanadyl sulfate (VOSO4∙3H2O) with dimethylmalonic (H2Me2mal = = C3H6(CO2H)2), cyclobutane-1,1-dicarboxylic (H2cbdc = C4H6(CO2H)2), or butylmalonic acid (H2Bumal = C4H10(CO2H)2) and Li2CO3 in a ratio of 1: 2: 2 afforded novel coordination polymers of similar compositions ([Li2(VO)(Me2mal)2]n (1), [Li2(VO)(Me2mal)2(EtOH)-(H2O)]n (2), [Li4(VO)2(cbdc)4(H2O)7]n (3), and [Li2(VO)(Bumal)2(H2O)5.5]n (4)) but different structures. The crystal structures of the compounds containing the Me2mal2– and Bumal2– anions depend on the solvent nature.
Об авторах
E. Bazhina
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: evgenia-VO@mail.ru
Россия, 31 Leninsky prosp., Moscow, 119991
G. Aleksandrov
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: evgenia-VO@mail.ru
Россия, 31 Leninsky prosp., Moscow, 119991
M. Kiskin
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: evgenia-VO@mail.ru
Россия, 31 Leninsky prosp., Moscow, 119991
A. Sidorov
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: evgenia-VO@mail.ru
Россия, 31 Leninsky prosp., Moscow, 119991
I. Eremenko
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: evgenia-VO@mail.ru
Россия, 31 Leninsky prosp., Moscow, 119991
Дополнительные файлы
