Synthesis and structure of bis(4-iodophenoxy)triphenylantimony and 4-iodophenoxytetraphenylantimony


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Abstract

A reaction of triphenylantimony with 4-iodophenol in the presence of hydrogen peroxide furnished bis(4-iodophenoxy)triphenylantimony, which when treated with pentaphenylantimony gave 4-iodophenoxytetraphenylantimony. The structure of organoantimony compounds was studied by 1H and 13C NMR spectroscopy and X-ray crystallography.

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V. V. Sharutin

South Ural State University

Author for correspondence.
Email: vvsharutin@rambler.ru
Russian Federation, 76 prosp. im. V. I. Lenina, Chelyabinsk, 454080

O. K. Sharutina

South Ural State University

Email: vvsharutin@rambler.ru
Russian Federation, 76 prosp. im. V. I. Lenina, Chelyabinsk, 454080

V. S. Senchurin

South Ural State University

Email: vvsharutin@rambler.ru
Russian Federation, 76 prosp. im. V. I. Lenina, Chelyabinsk, 454080

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