Coordination compounds of CuCl2 with 1-(N-heterylmethyl)silatranes


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Abstract

Reactions of CuCl2 with 1-(N-indolylmethyl)and 1-(N-carbazolylmethyl)silatranes (L) afforded new complexes CuCl2•L. Quantum chemical calculations of these complexes and a CuII complex with 1-(N-pyrrolylmethyl)silatrane showed that the Cu atom is coordinated to both the equatorial O atom of the silatranyl group and the π-system of the ligandś heterocycle.

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Yu. I. Bolgova

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Author for correspondence.
Email: omtrof@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033

E. F. Belogolova

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: omtrof@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033

V. V. Belyaeva

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: omtrof@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033

E. N. Timofeeva

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: omtrof@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033

O. M. Trofimova

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: omtrof@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033

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