Coordination compounds of CuCl2 with 1-(N-heterylmethyl)silatranes
- Authors: Bolgova Y.I.1, Belogolova E.F.1, Belyaeva V.V.1, Timofeeva E.N.1, Trofimova O.M.1
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Affiliations:
- A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
- Issue: Vol 65, No 4 (2016)
- Pages: 1039-1046
- Section: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/237837
- DOI: https://doi.org/10.1007/s11172-016-1410-3
- ID: 237837
Cite item
Abstract
Reactions of CuCl2 with 1-(N-indolylmethyl)and 1-(N-carbazolylmethyl)silatranes (L) afforded new complexes CuCl2•L. Quantum chemical calculations of these complexes and a CuII complex with 1-(N-pyrrolylmethyl)silatrane showed that the Cu atom is coordinated to both the equatorial O atom of the silatranyl group and the π-system of the ligandś heterocycle.
About the authors
Yu. I. Bolgova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Author for correspondence.
Email: omtrof@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033
E. F. Belogolova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: omtrof@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033
V. V. Belyaeva
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: omtrof@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033
E. N. Timofeeva
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: omtrof@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033
O. M. Trofimova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: omtrof@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033
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