Coordination compounds of CuCl2 with 1-(N-heterylmethyl)silatranes
- Autores: Bolgova Y.I.1, Belogolova E.F.1, Belyaeva V.V.1, Timofeeva E.N.1, Trofimova O.M.1
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Afiliações:
- A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
- Edição: Volume 65, Nº 4 (2016)
- Páginas: 1039-1046
- Seção: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/237837
- DOI: https://doi.org/10.1007/s11172-016-1410-3
- ID: 237837
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Resumo
Reactions of CuCl2 with 1-(N-indolylmethyl)and 1-(N-carbazolylmethyl)silatranes (L) afforded new complexes CuCl2•L. Quantum chemical calculations of these complexes and a CuII complex with 1-(N-pyrrolylmethyl)silatrane showed that the Cu atom is coordinated to both the equatorial O atom of the silatranyl group and the π-system of the ligandś heterocycle.
Sobre autores
Yu. Bolgova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Autor responsável pela correspondência
Email: omtrof@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
E. Belogolova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: omtrof@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
V. Belyaeva
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: omtrof@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
E. Timofeeva
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: omtrof@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
O. Trofimova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: omtrof@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
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