Selective fluorination of pyridine and its derivatives in the presence of high-oxidation-state transition metals
- Autores: Gryaznova T.V.1, Khrizanforova V.V.1, Kholin K.V.1, Khrizanforov M.N.1, Budnikova Y.H.1
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Afiliações:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- Edição: Volume 65, Nº 7 (2016)
- Páginas: 1798-1804
- Seção: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/238582
- DOI: https://doi.org/10.1007/s11172-016-1513-x
- ID: 238582
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Resumo
The oxidative fluorination of pyridine and 4-ethylpyridine under chemical and electro-chemical conditions in the presence of transition metal (high-oxidation-state nickel, cobalt, and silver) salts was studied. The chemical fluorination affords 2-fluoropyridine in all cases, while the electrochemical fluorination results in 2-fluoroor 3-fluoropyridine depending on the catalyst used.
Sobre autores
T. Gryaznova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Autor responsável pela correspondência
Email: tatyanag@iopc.ru
Rússia, 8 ul. Arbuzova, Kazan, 420088
V. Khrizanforova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
Rússia, 8 ul. Arbuzova, Kazan, 420088
K. Kholin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
Rússia, 8 ul. Arbuzova, Kazan, 420088
M. Khrizanforov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
Rússia, 8 ul. Arbuzova, Kazan, 420088
Yu. Budnikova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
Rússia, 8 ul. Arbuzova, Kazan, 420088
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