The enthalpies of formation and reorganization of aromatic radicals
- Авторы: Berlin A.A.1, Miroshnichenko E.A.1, Pashchenko L.L.2, Kon’kova T.S.1, Matyushin Y.N.1
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Учреждения:
- N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences
- Department of Chemistry, M. V. Lomonosov Moscow State University
- Выпуск: Том 65, № 8 (2016)
- Страницы: 1977-1980
- Раздел: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/238715
- DOI: https://doi.org/10.1007/s11172-016-1539-0
- ID: 238715
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Аннотация
The enthalpies of formation of some biphenyl derivatives were determined. A "double difference" method for calculating the enthalpies of formation of aromatic radicals and the bond dissociation energies was proposed. The enthalpies of formation of the radicals biphenyl, diphenyl oxide, and phenyl oxide were determined. The energies of reorganization of these radicals as well as phenyl and 4-, 3-, and 2-pyridyls were calculated. The sums of the energies of the chemical bonds in the molecular moieties transformed into radicals upon the decomposition of chemical compounds were found to be constant for different compounds. The energies of the chemical bonds in arenes were determined.
Об авторах
A. Berlin
N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences
Email: eamir02@mail.ru
Россия, 4 ul. Kosygina, Moscow, 119991
E. Miroshnichenko
N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: eamir02@mail.ru
Россия, 4 ul. Kosygina, Moscow, 119991
L. Pashchenko
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: eamir02@mail.ru
Россия, 1 Leninskie Gory, Moscow, 119991
T. Kon’kova
N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences
Email: eamir02@mail.ru
Россия, 4 ul. Kosygina, Moscow, 119991
Yu. Matyushin
N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences
Email: eamir02@mail.ru
Россия, 4 ul. Kosygina, Moscow, 119991
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