Structural studies of 1,3-oxazolidine-containing spiropyrans


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Abstract

New 3’-(4-chlorophenyl)-5’,5’-dimethyl-2’-oxospiro[(2H)-chromene-2,4’-1,3-oxazolidine] was synthesized to study the donor influence of the chlorine atom at the N-phenyl substituent on the structure and photochromic properties of 1,3-oxazolidine-containing spiropyrans. Photochemical properties of synthesized 1,3-oxazolidine derivatives were studied at room temperature in toluene. The X-ray diffraction parameters for the new compound were compared with the data obtained earlier for similar spiropyrans.

About the authors

B. S. Luk’yanov

Institute of Physical and Organic Chemistry, Southern Federal University

Author for correspondence.
Email: bluk@ipoc.sfedu.ru
Russian Federation, 194/2 prosp. Stachki, Rostov on Don, 344090

V. V. Tkachev

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: bluk@ipoc.sfedu.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

M. B. Luk’yanova

Institute of Physical and Organic Chemistry, Southern Federal University

Email: bluk@ipoc.sfedu.ru
Russian Federation, 194/2 prosp. Stachki, Rostov on Don, 344090

A. N. Utenyshev

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: bluk@ipoc.sfedu.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

R. V. Tyurin

Institute of Physical and Organic Chemistry, Southern Federal University

Email: bluk@ipoc.sfedu.ru
Russian Federation, 194/2 prosp. Stachki, Rostov on Don, 344090

M. S. Korobov

Institute of Physical and Organic Chemistry, Southern Federal University

Email: bluk@ipoc.sfedu.ru
Russian Federation, 194/2 prosp. Stachki, Rostov on Don, 344090

S. M. Aldoshin

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: bluk@ipoc.sfedu.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

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