Nitration of sulfate lignin under homogeneous conditions studied by electron spectroscopy
- Authors: Khabarov Y.G.1, Kuzyakov N.Y.1, Veshnyakov V.A.1, Komarova G.V.1, Garkotin A.Y.1
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Affiliations:
- Northern (Arctic) Federal University named after M. V. Lomonosov
- Issue: Vol 65, No 12 (2016)
- Pages: 2925-2931
- Section: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/239643
- DOI: https://doi.org/10.1007/s11172-016-1679-2
- ID: 239643
Cite item
Abstract
The nitration of sulfate lignin by nitric acid in an aqueous-dioxane medium under homogeneous conditions was studied. The method proposed makes it possible to synthesize nitrated lignin with the content of one nitro group per 1.5–2 phenylpropane units. At low consumptions of nitric acid, the nitration starts after an induction period, the duration of which decreases with increasing temperature. The presence of the induction period is related to redox transformations forming nitrous acid that nitrosates lignin.
About the authors
Yu. G. Khabarov
Northern (Arctic) Federal University named after M. V. Lomonosov
Author for correspondence.
Email: khabarov.yu@mail.ru
Russian Federation, 17 nab. Severnoi Dviny, Arkhangelsk, 163002
N. Yu. Kuzyakov
Northern (Arctic) Federal University named after M. V. Lomonosov
Email: khabarov.yu@mail.ru
Russian Federation, 17 nab. Severnoi Dviny, Arkhangelsk, 163002
V. A. Veshnyakov
Northern (Arctic) Federal University named after M. V. Lomonosov
Email: khabarov.yu@mail.ru
Russian Federation, 17 nab. Severnoi Dviny, Arkhangelsk, 163002
G. V. Komarova
Northern (Arctic) Federal University named after M. V. Lomonosov
Email: khabarov.yu@mail.ru
Russian Federation, 17 nab. Severnoi Dviny, Arkhangelsk, 163002
A. Yu. Garkotin
Northern (Arctic) Federal University named after M. V. Lomonosov
Email: khabarov.yu@mail.ru
Russian Federation, 17 nab. Severnoi Dviny, Arkhangelsk, 163002
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