Email this article Study of the reactivity of organonickel sigma-complexes towards nitriles
- Authors: Gafurov Z.N.1,2, Sakhapov I.F.1,2, Babaev V.M.1, Dobrynin A.B.1, Kurmaz V.A.3, Metlushka K.E.1, Rizvanov I.K.1, Shaikhutdinova G.R.1, Sinyashin O.G.1, Yakhvarov D.G.1,2
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Affiliations:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences
- A. M. Butlerov Institute of Chemistry, Kazan Federal University
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Issue: Vol 66, No 2 (2017)
- Pages: 254-259
- Section: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/239977
- DOI: https://doi.org/10.1007/s11172-017-1725-8
- ID: 239977
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Abstract
The reactivity of organonickel sigma-complexes of type [NiBr(Ar)(bpy)], where Ar = 2,6-dimethylphenyl (Xyl), 2,4,6-trimethylphenyl (Mes), 2,4,6-triisopropylphenyl (Tipp), 2,4,6-tricyclohexylphenyl (Tchp), bpy = 2,2´-bipyridine, towards nitriles (acetonitrile, propionitrile, chloroacetonitrile, benzonitrile) has been investigated. This reaction leads to imines by formation of new carbon—carbon bond between aromatic fragment and nitrile group C≡N.
About the authors
Z. N. Gafurov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences; A. M. Butlerov Institute of Chemistry, Kazan Federal University
Email: yakhvar@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008
I. F. Sakhapov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences; A. M. Butlerov Institute of Chemistry, Kazan Federal University
Email: yakhvar@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008
V. M. Babaev
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences
Email: yakhvar@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
A. B. Dobrynin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences
Email: yakhvar@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
V. A. Kurmaz
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: yakhvar@iopc.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow region, 142432
K. E. Metlushka
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences
Email: yakhvar@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
I. Kh. Rizvanov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences
Email: yakhvar@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
G. R. Shaikhutdinova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences
Email: yakhvar@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
O. G. Sinyashin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences
Email: yakhvar@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
D. G. Yakhvarov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences; A. M. Butlerov Institute of Chemistry, Kazan Federal University
Author for correspondence.
Email: yakhvar@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008
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