Synthesis of new binuclear tricarbonylchromium- and -manganese complexes of isoxazolidines by 1,3-dipolar cycloaddition reaction


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Abstract

The reactions of 1,3-dipolar cycloaddition of π-complexes of nitrones of a general formula R2CH=N(O)R1, where R1 = Me, But, Ph, R2 = Ph[Cr(CO)3], C5H4[Mn(CO)3] with (η6-styrene)-tricarbonylchromium and vinyl-(η5-cyclopentadienyl)tricarbonylmanganese have been investigated. These reactions led to the formation of corresponding isoxazolidines with high regio- and diastereoselectivity. The obtained metal-containing isoxazolidines were identified using UV, IR, 1H NMR spectroscopy, mass-spectrometry, and X-ray diffraction analysis.

About the authors

N. Yu. Grishina

N. I. Lobachevsky State University of Nizhny Novgorod

Author for correspondence.
Email: zarovkinan@mail.ru
Russian Federation, 5 korp., 23 prosp. Gagarina, Nizhny Novgorod, 603950

E. V. Sazonova

N. I. Lobachevsky State University of Nizhny Novgorod

Email: zarovkinan@mail.ru
Russian Federation, 5 korp., 23 prosp. Gagarina, Nizhny Novgorod, 603950

A. N. Artemov

N. I. Lobachevsky State University of Nizhny Novgorod

Email: zarovkinan@mail.ru
Russian Federation, 5 korp., 23 prosp. Gagarina, Nizhny Novgorod, 603950

G. K. Fukin

N. I. Lobachevsky State University of Nizhny Novgorod; G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: zarovkinan@mail.ru
Russian Federation, 5 korp., 23 prosp. Gagarina, Nizhny Novgorod, 603950; 49 ul. Tropinina, Nizhny Novgorod, 603137

V. I. Faerman

N. I. Lobachevsky State University of Nizhny Novgorod

Email: zarovkinan@mail.ru
Russian Federation, 5 korp., 23 prosp. Gagarina, Nizhny Novgorod, 603950

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