Email this article Phase-transfer Tsuji—Trost allylation of CH-acids with the assistance of palladium complexes with bidentate PIII—N—PIII ligands
- Authors: Vasil´ev A.A.1, Aladzheva I.M.2, Bykhovskaya O.V.2
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Affiliations:
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Issue: Vol 66, No 4 (2017)
- Pages: 661-665
- Section: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/240391
- DOI: https://doi.org/10.1007/s11172-017-1788-6
- ID: 240391
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Abstract
The Tsuji—Trost allylation of CH acids, in particular, those of the YCH2CO2Et type (Y = CO2Et, C(O)Me, CN), with allylic acetates in the K2CO3—DMF system in the presence of palladium catalysts with ligands RN(PPh2)2 (R = Ph, Pri, c-C6H11) is accomplished.
About the authors
A. A. Vasil´ev
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: vasiliev@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
I. M. Aladzheva
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: vasiliev@ioc.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
O. V. Bykhovskaya
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: vasiliev@ioc.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
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