Stereochemistry of chromium complexes with monosubstituted allenes


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Previously unknown arenechromium dicarbonyl complexes with different allenes including functionally substituted ones were synthesized. The formed compounds represent a mixture of all three possible isomers and exhibit stereochemical nonrigidity. The isomerization process and stereochemical peculiarities of the complexes synthesized were studied using the 1H NMR method.

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V. Krivykh

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

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Email: vkriv@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991

E. Taits

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: vkriv@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991

P. Petrovskii

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: vkriv@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991

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