Email this article Organic conductor θ-(BEDT-TTF)Cd1.38I3 with layered perovskite-like structure
- Authors: Zhilyaeva E.I.1, Shilov G.V.1, Flakina A.M.1, Lyubovskaya R.N.1
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Affiliations:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Issue: Vol 67, No 2 (2018)
- Pages: 252-254
- Section: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/242103
- DOI: https://doi.org/10.1007/s11172-018-2066-y
- ID: 242103
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Abstract
The organic conductor θ-(BEDT-TTF)Cd1.38I3 (1) (BEDT-TTF is bis(ethylenedithio)- tetrathiafulvalene) with layered perovskite-like structure was synthesized. In the crystal structure of 1, θ-type organic conducting layers, which are built up from BEDT-TTF stacks, alternate with inorganic insulating layers. The latter are composed of CdI6 octahedra and CdI4 tetrahedra linked together to form a two-dimensional anionic network. Measurements of the temperature dependence of the electrical resistance demonstrated that compound 1 is a semiconductor.
About the authors
E. I. Zhilyaeva
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Author for correspondence.
Email: zhilya@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
G. V. Shilov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: zhilya@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
A. M. Flakina
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: zhilya@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
R. N. Lyubovskaya
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: zhilya@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
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