Organic conductor θ-(BEDT-TTF)Cd1.38I3 with layered perovskite-like structure


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The organic conductor θ-(BEDT-TTF)Cd1.38I3 (1) (BEDT-TTF is bis(ethylenedithio)- tetrathiafulvalene) with layered perovskite-like structure was synthesized. In the crystal structure of 1, θ-type organic conducting layers, which are built up from BEDT-TTF stacks, alternate with inorganic insulating layers. The latter are composed of CdI6 octahedra and CdI4 tetrahedra linked together to form a two-dimensional anionic network. Measurements of the temperature dependence of the electrical resistance demonstrated that compound 1 is a semiconductor.

Sobre autores

E. Zhilyaeva

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Autor responsável pela correspondência
Email: zhilya@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

G. Shilov

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: zhilya@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

A. Flakina

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: zhilya@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

R. Lyubovskaya

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: zhilya@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

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