The necessary and sufficient conditions for chemical equilibrium

E. A. Smolenskii; A. N. Ryzhov; I. V. Chuvaeva; L. K. Maslova; A. L. Lapidus

doi:10.1007/s11172-018-2165-9

The necessary and sufficient conditions for chemical equilibrium

Authors: Smolenskii E.A.¹, Ryzhov A.N.¹, Chuvaeva I.V.¹, Maslova L.K.¹, Lapidus A.L.¹
Affiliations:
1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Issue: Vol 67, No 6 (2018)
Pages: 966-971
Section: Full Articles
URL: https://journal-vniispk.ru/1066-5285/article/view/242570
DOI: https://doi.org/10.1007/s11172-018-2165-9
ID: 242570

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Abstract

The article concerns a widely accepted but incorrect concept of conditions for chemical equilibrium. The authors present a mathematically rigorous derivation of the necessary and sufficient conditions for chemical equilibrium of systems of arbitrary complexity.