Thermal decomposition of ammonium perchlorate in the presence of bimetallic additives


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Abstract

The catalytic activity of the thermolysis products of double complex compounds in the decomposition reaction of ammonium perchlorate was studied. The products used are C1.4N1.6H3CoFe (I), C6N8Co4Fe3 (II), O11Co4Fe3 (III), O8.5(CN)0.3Cu3Fe2 (IV), and reactive CuO. All active phases decrease the temperature of complete decomposition of NH4ClO4, and the order of temperature decreasing is the following: III (120 °C) > IV > III (80 °C) ≫ CuO.

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D. P. Domonov

I. V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center of the Russian Academy of Sciences

Author for correspondence.
Email: domonov@chemy.kolasc.net.ru
Russian Federation, 26a Akademgorodok, Apatity, 184209

S. I. Pechenyuk

I. V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center of the Russian Academy of Sciences

Email: domonov@chemy.kolasc.net.ru
Russian Federation, 26a Akademgorodok, Apatity, 184209

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