Отправить статью по E-mail Mechanism of electrochemical reduction of 5-thio derivatives of 2(5H)-furanone
- Авторы: Latypova L.Z.1, Chmutova G.A.1, Kurbangalieva A.R.1, Yanilkin V.V.2
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Учреждения:
- A. M. Butlerov Institute of Chemistry, Kazan Federal University
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”
- Выпуск: Том 68, № 2 (2019)
- Страницы: 313-327
- Раздел: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/243248
- DOI: https://doi.org/10.1007/s11172-019-2387-5
- ID: 243248
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Аннотация
The anionoid elimination of the substituent from position 5 of the lactone ring is the predominant pathway of electrochemical reduction of 5-arylsulfanyl- and 5-arylsulfonyl-3,4-dichloro-2(5H)-furanones in acetonitrile. The contribution of the competing elimination of the chloride ion increases on going to 3,4-dichloro-5-ethylsulfanyl-2(5H)-furanone. An experimental criterion based on the morphology of cyclic voltammograms was proposed for identification of a particular pathway of electroreduction of 2(5H)-furanone derivatives.
Об авторах
L. Latypova
A. M. Butlerov Institute of Chemistry, Kazan Federal University
Автор, ответственный за переписку.
Email: llatypov@kpfu.ru
Россия, 18 ul. Kremlevskaya, Kazan, 420008
G. Chmutova
A. M. Butlerov Institute of Chemistry, Kazan Federal University
Email: llatypov@kpfu.ru
Россия, 18 ul. Kremlevskaya, Kazan, 420008
A. Kurbangalieva
A. M. Butlerov Institute of Chemistry, Kazan Federal University
Email: llatypov@kpfu.ru
Россия, 18 ul. Kremlevskaya, Kazan, 420008
V. Yanilkin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”
Email: llatypov@kpfu.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
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