电邮这篇文章 Asymmetric Michael reaction between aldehydes and nitroalkanes promoted by pyrrolidine-containing C2-symmetric organocatalysts
- 作者: Bykova K.A.1,2, Kostenko A.A.1, Kucherenko A.S.1, Zlotin S.G.1
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隶属关系:
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Dmitry Mendeleev University of Chemical Technology of Russia
- 期: 卷 68, 编号 7 (2019)
- 页面: 1402-1406
- 栏目: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/243429
- DOI: https://doi.org/10.1007/s11172-019-2568-2
- ID: 243429
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详细
Bifunctional C2-symmetric organocatalysts derived from chiral 1,2-diaminoethanes and (S)-2-aminomethylpyrrolidine were fi rst used for promoting the asymmetric Michael addition of aliphatic aldehydes to nitroalkenes. The synthesized enantioenriched (up to 82% ee) products can be transformed into various biologically active γ-aminobutyric acid derivatives.
作者简介
K. Bykova
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences; Dmitry Mendeleev University of Chemical Technology of Russia
Email: bykova_ksyusha@mail.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991; 9 Miusskaya pl., Moscow, 125047
A. Kostenko
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: bykova_ksyusha@mail.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991
A. Kucherenko
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: bykova_ksyusha@mail.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991
S. Zlotin
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: bykova_ksyusha@mail.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991
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