Reactions of chloromethoxy-substituted 3-(2-acetoxyethyl)-1-hydroxytriaz-1-ene 2-oxides with 1-alkoxy-3-(2-hydroxyethyl)triaz-1-ene 2-oxide alkali salts


Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

Reactions of 1-alkoxy-3-(2-hydroxyethyl)triaz-1-ene 2-oxides and 1-chloromethoxytriaz1-ene 2-oxides with chloromethoxy derivatives of 3-alkyl-3-(2-acetoxyethyl)- and 3,3-bis(2-acetoxyethyl)-1-hydroxytriaz-1-ene 2-oxides result in very complex product mixtures with the major product comprising the starting salt fragments linked by a methylene bridge. In these products, the central methylene group bridges either two oxygen atoms or two nitrogen atoms, or one oxygen and one nitrogen atom. The synthesized compounds contain from two to four 2-hydroxyethyl moieties.

About the authors

G. A. Smirnov

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: smir@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991

P. B. Gordeev

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: smir@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991

S. V. Nikitin

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: smir@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991

G. V. Pokhvisneva

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: smir@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991

T. V. Ternikova

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: smir@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991

O. A. Luk’yanov

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: smir@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2016 Springer Science+Business Media New York