Sorption of Manganese Cations by Modified Humic Acids from Lignite


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Abstract

The sorption of Mn2+ ions from aqueous solutions of humic acids derived from Tisul’sk lignite is investigated. The influence of treatment of the humic acids by hydrogen peroxide on their sorptional characteristics is considered. The sorptional capacity of modified and unmodified humic acids for the manganese cation is determined. IR, NMR, and ESR spectroscopy shows that the greater sorptional capacity of humic acids after modification by hydrogen peroxide may be attributed to change in their functional composition.

About the authors

S. I. Zherebtsov

Federal Research Center of Coal and Coal Chemistry, Siberian Branch

Author for correspondence.
Email: sizh@yandex.ru
Russian Federation, Kemerovo

N. V. Malyshenko

Federal Research Center of Coal and Coal Chemistry, Siberian Branch

Email: sizh@yandex.ru
Russian Federation, Kemerovo

L. V. Bryukhovetskaya

Federal Research Center of Coal and Coal Chemistry, Siberian Branch

Email: sizh@yandex.ru
Russian Federation, Kemerovo

Z. R. Ismagilov

Federal Research Center of Coal and Coal Chemistry, Siberian Branch

Email: sizh@yandex.ru
Russian Federation, Kemerovo

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