Compounds of the menthane series. Synthesis of unsaturated primary alcohols with the o- and p-menthane skeletons
- Authors: Fedorov P.I.1, Fedorova T.P.1, Sheverdov V.P.1, Pavlov G.P.1, Eremkin A.V.1
-
Affiliations:
- I.N. Ul’yanov Chuvash State University
- Issue: Vol 52, No 6 (2016)
- Pages: 806-812
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/214468
- DOI: https://doi.org/10.1134/S1070428016060075
- ID: 214468
Cite item
Abstract
Precursors to terpene alcohols of the o- and p-menthane series (o-cimen-7-ol and o- and p-cimen-9-ols) were synthesized, and their reduction with lithium in ethylenediamine was studied. The reduction of o- and p-cimen-9-ols in the presence of isopropyl alcohol selectively afforded the corresponding 1,4-dihydro derivatives. Under analogous conditions, o-cimen-7-ol was converted into a mixture of unsaturated hydrocarbons. The reduction with lithium in ethylenediamine in the absence of isopropyl alcohol in all cases gave mixtures of menthene alcohols.
About the authors
P. I. Fedorov
I.N. Ul’yanov Chuvash State University
Author for correspondence.
Email: paf@myrambler.ru
Russian Federation, Moskovskii pr. 15, Cheboksary, 428015
T. P. Fedorova
I.N. Ul’yanov Chuvash State University
Email: paf@myrambler.ru
Russian Federation, Moskovskii pr. 15, Cheboksary, 428015
V. P. Sheverdov
I.N. Ul’yanov Chuvash State University
Email: paf@myrambler.ru
Russian Federation, Moskovskii pr. 15, Cheboksary, 428015
G. P. Pavlov
I.N. Ul’yanov Chuvash State University
Email: paf@myrambler.ru
Russian Federation, Moskovskii pr. 15, Cheboksary, 428015
A. V. Eremkin
I.N. Ul’yanov Chuvash State University
Email: paf@myrambler.ru
Russian Federation, Moskovskii pr. 15, Cheboksary, 428015
Supplementary files
