Compounds of the menthane series. Synthesis of unsaturated primary alcohols with the o- and p-menthane skeletons
- Autores: Fedorov P.I.1, Fedorova T.P.1, Sheverdov V.P.1, Pavlov G.P.1, Eremkin A.V.1
-
Afiliações:
- I.N. Ul’yanov Chuvash State University
- Edição: Volume 52, Nº 6 (2016)
- Páginas: 806-812
- Seção: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/214468
- DOI: https://doi.org/10.1134/S1070428016060075
- ID: 214468
Citar
Resumo
Precursors to terpene alcohols of the o- and p-menthane series (o-cimen-7-ol and o- and p-cimen-9-ols) were synthesized, and their reduction with lithium in ethylenediamine was studied. The reduction of o- and p-cimen-9-ols in the presence of isopropyl alcohol selectively afforded the corresponding 1,4-dihydro derivatives. Under analogous conditions, o-cimen-7-ol was converted into a mixture of unsaturated hydrocarbons. The reduction with lithium in ethylenediamine in the absence of isopropyl alcohol in all cases gave mixtures of menthene alcohols.
Sobre autores
P. Fedorov
I.N. Ul’yanov Chuvash State University
Autor responsável pela correspondência
Email: paf@myrambler.ru
Rússia, Moskovskii pr. 15, Cheboksary, 428015
T. Fedorova
I.N. Ul’yanov Chuvash State University
Email: paf@myrambler.ru
Rússia, Moskovskii pr. 15, Cheboksary, 428015
V. Sheverdov
I.N. Ul’yanov Chuvash State University
Email: paf@myrambler.ru
Rússia, Moskovskii pr. 15, Cheboksary, 428015
G. Pavlov
I.N. Ul’yanov Chuvash State University
Email: paf@myrambler.ru
Rússia, Moskovskii pr. 15, Cheboksary, 428015
A. Eremkin
I.N. Ul’yanov Chuvash State University
Email: paf@myrambler.ru
Rússia, Moskovskii pr. 15, Cheboksary, 428015
Arquivos suplementares
