Email this article Regiospecific allyl chlorination of betulin and diacetylbetulin
- Authors: Kurskii Y.A.1,2, Bodrikov I.V.1, Chiyanov A.A.3, Bazhan L.I.1
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Affiliations:
- Nizhny Novgorod State Technical University n. a. R.E. Alekseev
- G.A. Razuvaev Institute of Organometallic Chemistry
- Lobachevsky State University of Nizhny Novgorod
- Issue: Vol 53, No 2 (2017)
- Pages: 303-304
- Section: Short Communications
- URL: https://journal-vniispk.ru/1070-4280/article/view/215858
- DOI: https://doi.org/10.1134/S1070428017020294
- ID: 215858
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Abstract
For the first time it was established that in the reaction of selenium dichloride with betulin and diacetylbetulin it is realized regiospecific allylic substitution of hydrogen in these alkenes by chlorine atom with formation of a single product–an unsaturated chloride of allylic type. The structure of products was proved by 1Н NMR spectra.
About the authors
Yu. A. Kurskii
Nizhny Novgorod State Technical University n. a. R.E. Alekseev; G.A. Razuvaev Institute of Organometallic Chemistry
Email: orgchim@nntu.ru
Russian Federation, ul. Minina 24, Nizhny Novgorod, 603950; Nizhny Novgorod
I. V. Bodrikov
Nizhny Novgorod State Technical University n. a. R.E. Alekseev
Email: orgchim@nntu.ru
Russian Federation, ul. Minina 24, Nizhny Novgorod, 603950
A. A. Chiyanov
Lobachevsky State University of Nizhny Novgorod
Email: orgchim@nntu.ru
Russian Federation, Nizhny Novgorod
L. I. Bazhan
Nizhny Novgorod State Technical University n. a. R.E. Alekseev
Author for correspondence.
Email: orgchim@nntu.ru
Russian Federation, ul. Minina 24, Nizhny Novgorod, 603950
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