Regiospecific allyl chlorination of betulin and diacetylbetulin
- 作者: Kurskii Y.A.1,2, Bodrikov I.V.1, Chiyanov A.A.3, Bazhan L.I.1
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隶属关系:
- Nizhny Novgorod State Technical University n. a. R.E. Alekseev
- G.A. Razuvaev Institute of Organometallic Chemistry
- Lobachevsky State University of Nizhny Novgorod
- 期: 卷 53, 编号 2 (2017)
- 页面: 303-304
- 栏目: Short Communications
- URL: https://journal-vniispk.ru/1070-4280/article/view/215858
- DOI: https://doi.org/10.1134/S1070428017020294
- ID: 215858
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详细
For the first time it was established that in the reaction of selenium dichloride with betulin and diacetylbetulin it is realized regiospecific allylic substitution of hydrogen in these alkenes by chlorine atom with formation of a single product–an unsaturated chloride of allylic type. The structure of products was proved by 1Н NMR spectra.
作者简介
Yu. Kurskii
Nizhny Novgorod State Technical University n. a. R.E. Alekseev; G.A. Razuvaev Institute of Organometallic Chemistry
Email: orgchim@nntu.ru
俄罗斯联邦, ul. Minina 24, Nizhny Novgorod, 603950; Nizhny Novgorod
I. Bodrikov
Nizhny Novgorod State Technical University n. a. R.E. Alekseev
Email: orgchim@nntu.ru
俄罗斯联邦, ul. Minina 24, Nizhny Novgorod, 603950
A. Chiyanov
Lobachevsky State University of Nizhny Novgorod
Email: orgchim@nntu.ru
俄罗斯联邦, Nizhny Novgorod
L. Bazhan
Nizhny Novgorod State Technical University n. a. R.E. Alekseev
编辑信件的主要联系方式.
Email: orgchim@nntu.ru
俄罗斯联邦, ul. Minina 24, Nizhny Novgorod, 603950
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