Unexpected Regioselective Reactions of 2-(Bromomethyl)-1,3-thiaselenole with 1-Methyl-1 H -imidazol-2-thiol, Accompanied by Rearrangements

S. V. Amosova; A. S. Filippov; V. A. Potapov; N. A. Makhaeva; A. I. Albanov

doi:10.1134/S107042801811012X

Unexpected Regioselective Reactions of 2-(Bromomethyl)-1,3-thiaselenole with 1-Methyl-1H-imidazol-2-thiol, Accompanied by Rearrangements

Authors: Amosova S.V.¹, Filippov A.S.¹, Potapov V.A.¹, Makhaeva N.A.¹, Albanov A.I.¹
Affiliations:
1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Issue: Vol 54, No 11 (2018)
Pages: 1697-1701
Section: Article
URL: https://journal-vniispk.ru/1070-4280/article/view/219414
DOI: https://doi.org/10.1134/S107042801811012X
ID: 219414

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Abstract

The previously unknown regioselective reactions of 2-(bromomethyl)-1,3-thiaselenole with 1-methyl-1H-imidazol-2-thiol were used to develop efficient synthetic approaches to novel heterocyclic systems, involving C–S and C–N bond formation. The reactions are accompanied by the rearrangements of the starting heterocycles, giving rise to diverse potentially biologically active heterocyclic systems.