Unexpected Regioselective Reactions of 2-(Bromomethyl)-1,3-thiaselenole with 1-Methyl-1 H -imidazol-2-thiol, Accompanied by Rearrangements

S. V. Amosova; A. S. Filippov; V. A. Potapov; N. A. Makhaeva; A. I. Albanov

doi:10.1134/S107042801811012X

Unexpected Regioselective Reactions of 2-(Bromomethyl)-1,3-thiaselenole with 1-Methyl-1H-imidazol-2-thiol, Accompanied by Rearrangements

作者: Amosova S.V.¹, Filippov A.S.¹, Potapov V.A.¹, Makhaeva N.A.¹, Albanov A.I.¹
隶属关系:
1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
期: 卷 54, 编号 11 (2018)
页面: 1697-1701
栏目: Article
URL: https://journal-vniispk.ru/1070-4280/article/view/219414
DOI: https://doi.org/10.1134/S107042801811012X
ID: 219414

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详细

The previously unknown regioselective reactions of 2-(bromomethyl)-1,3-thiaselenole with 1-methyl-1H-imidazol-2-thiol were used to develop efficient synthetic approaches to novel heterocyclic systems, involving C–S and C–N bond formation. The reactions are accompanied by the rearrangements of the starting heterocycles, giving rise to diverse potentially biologically active heterocyclic systems.