Email this article Kinetics and thermochemistry of [2π + 2σ + 2σ]-cycloaddition of quadricyclane to tetracyanoethylene
- Authors: Kiselev V.D.1, Kornilov D.A.1, Anikin O.V.1, Latypova L.I.1, Bermeshev M.V.2, Chapala P.P.2, Konovalov A.I.3
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Affiliations:
- Butlerov Institute of Chemistry
- Topchiev Institute of Petrochemical Synthesis
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
- Issue: Vol 52, No 6 (2016)
- Pages: 777-780
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/214453
- DOI: https://doi.org/10.1134/S1070428016060038
- ID: 214453
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Abstract
Kinetic data for the unusual [2π + 2σ + 2σ]-cycloaddition of quadricyclane to tetracyanoethylene in toluene have been obtained for the first time. The same reaction in 1,4-dioxane appears to be the most exothermic among known cycloaddition reactions. The entropy of activation and reaction volume differ only slightly from the corresponding parameters of conventional Diels–Alder reactions.
About the authors
V. D. Kiselev
Butlerov Institute of Chemistry
Author for correspondence.
Email: vkiselev.ksu@gmail.com
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
D. A. Kornilov
Butlerov Institute of Chemistry
Email: vkiselev.ksu@gmail.com
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
O. V. Anikin
Butlerov Institute of Chemistry
Email: vkiselev.ksu@gmail.com
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
L. I. Latypova
Butlerov Institute of Chemistry
Email: vkiselev.ksu@gmail.com
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
M. V. Bermeshev
Topchiev Institute of Petrochemical Synthesis
Email: vkiselev.ksu@gmail.com
Russian Federation, Leninskii pr. 29, Moscow, 119991
P. P. Chapala
Topchiev Institute of Petrochemical Synthesis
Email: vkiselev.ksu@gmail.com
Russian Federation, Leninskii pr. 29, Moscow, 119991
A. I. Konovalov
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: vkiselev.ksu@gmail.com
Russian Federation, ul. Arbuzova 8, Tatarstan, Kazan, 420088
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