电邮这篇文章 Kinetics and thermochemistry of [2π + 2σ + 2σ]-cycloaddition of quadricyclane to tetracyanoethylene
- 作者: Kiselev V.D.1, Kornilov D.A.1, Anikin O.V.1, Latypova L.I.1, Bermeshev M.V.2, Chapala P.P.2, Konovalov A.I.3
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隶属关系:
- Butlerov Institute of Chemistry
- Topchiev Institute of Petrochemical Synthesis
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
- 期: 卷 52, 编号 6 (2016)
- 页面: 777-780
- 栏目: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/214453
- DOI: https://doi.org/10.1134/S1070428016060038
- ID: 214453
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详细
Kinetic data for the unusual [2π + 2σ + 2σ]-cycloaddition of quadricyclane to tetracyanoethylene in toluene have been obtained for the first time. The same reaction in 1,4-dioxane appears to be the most exothermic among known cycloaddition reactions. The entropy of activation and reaction volume differ only slightly from the corresponding parameters of conventional Diels–Alder reactions.
作者简介
V. Kiselev
Butlerov Institute of Chemistry
编辑信件的主要联系方式.
Email: vkiselev.ksu@gmail.com
俄罗斯联邦, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
D. Kornilov
Butlerov Institute of Chemistry
Email: vkiselev.ksu@gmail.com
俄罗斯联邦, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
O. Anikin
Butlerov Institute of Chemistry
Email: vkiselev.ksu@gmail.com
俄罗斯联邦, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
L. Latypova
Butlerov Institute of Chemistry
Email: vkiselev.ksu@gmail.com
俄罗斯联邦, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
M. Bermeshev
Topchiev Institute of Petrochemical Synthesis
Email: vkiselev.ksu@gmail.com
俄罗斯联邦, Leninskii pr. 29, Moscow, 119991
P. Chapala
Topchiev Institute of Petrochemical Synthesis
Email: vkiselev.ksu@gmail.com
俄罗斯联邦, Leninskii pr. 29, Moscow, 119991
A. Konovalov
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: vkiselev.ksu@gmail.com
俄罗斯联邦, ul. Arbuzova 8, Tatarstan, Kazan, 420088
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