Отправить статью по E-mail Kinetics and thermochemistry of [2π + 2σ + 2σ]-cycloaddition of quadricyclane to tetracyanoethylene
- Авторы: Kiselev V.D.1, Kornilov D.A.1, Anikin O.V.1, Latypova L.I.1, Bermeshev M.V.2, Chapala P.P.2, Konovalov A.I.3
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Учреждения:
- Butlerov Institute of Chemistry
- Topchiev Institute of Petrochemical Synthesis
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
- Выпуск: Том 52, № 6 (2016)
- Страницы: 777-780
- Раздел: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/214453
- DOI: https://doi.org/10.1134/S1070428016060038
- ID: 214453
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Аннотация
Kinetic data for the unusual [2π + 2σ + 2σ]-cycloaddition of quadricyclane to tetracyanoethylene in toluene have been obtained for the first time. The same reaction in 1,4-dioxane appears to be the most exothermic among known cycloaddition reactions. The entropy of activation and reaction volume differ only slightly from the corresponding parameters of conventional Diels–Alder reactions.
Об авторах
V. Kiselev
Butlerov Institute of Chemistry
Автор, ответственный за переписку.
Email: vkiselev.ksu@gmail.com
Россия, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
D. Kornilov
Butlerov Institute of Chemistry
Email: vkiselev.ksu@gmail.com
Россия, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
O. Anikin
Butlerov Institute of Chemistry
Email: vkiselev.ksu@gmail.com
Россия, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
L. Latypova
Butlerov Institute of Chemistry
Email: vkiselev.ksu@gmail.com
Россия, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
M. Bermeshev
Topchiev Institute of Petrochemical Synthesis
Email: vkiselev.ksu@gmail.com
Россия, Leninskii pr. 29, Moscow, 119991
P. Chapala
Topchiev Institute of Petrochemical Synthesis
Email: vkiselev.ksu@gmail.com
Россия, Leninskii pr. 29, Moscow, 119991
A. Konovalov
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: vkiselev.ksu@gmail.com
Россия, ul. Arbuzova 8, Tatarstan, Kazan, 420088
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