Synthesis of Amides by Nucleophilic Substitution of Hydrogen in 3-Nitropyridine

G. A. Amangasieva; I. V. Borovlev; O. P. Demidov; E. K. Avakyan; A. A. Borovleva

doi:10.1134/S1070428018060076

Synthesis of Amides by Nucleophilic Substitution of Hydrogen in 3-Nitropyridine

作者: Amangasieva G.A.¹, Borovlev I.V.¹, Demidov O.P.¹, Avakyan E.K.¹, Borovleva A.A.¹
隶属关系:
1. North Caucasus Federal University
期: 卷 54, 编号 6 (2018)
页面: 867-872
栏目: Article
URL: https://journal-vniispk.ru/1070-4280/article/view/218062
DOI: https://doi.org/10.1134/S1070428018060076
ID: 218062

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详细

3-Nitropyridine reacted with nitrogen-centered carboxylic acid amide anions in anhydrous DMSO in the presence of K₃Fe(CN)₆ via oxidative nucleophilic substitution of hydrogen to give previously unknown N-(5-nitropyridin-2-yl) carboxamides. The reaction of nitrobenzene with urea anion in DMSO enabled one-pot synthesis of bis(4-nitrophenyl)amine.