Email this article Synthesis of Amides by Nucleophilic Substitution of Hydrogen in 3-Nitropyridine
- Authors: Amangasieva G.A.1, Borovlev I.V.1, Demidov O.P.1, Avakyan E.K.1, Borovleva A.A.1
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Affiliations:
- North Caucasus Federal University
- Issue: Vol 54, No 6 (2018)
- Pages: 867-872
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/218062
- DOI: https://doi.org/10.1134/S1070428018060076
- ID: 218062
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Abstract
3-Nitropyridine reacted with nitrogen-centered carboxylic acid amide anions in anhydrous DMSO in the presence of K3Fe(CN)6 via oxidative nucleophilic substitution of hydrogen to give previously unknown N-(5-nitropyridin-2-yl) carboxamides. The reaction of nitrobenzene with urea anion in DMSO enabled one-pot synthesis of bis(4-nitrophenyl)amine.
About the authors
G. A. Amangasieva
North Caucasus Federal University
Email: ivborovlev@rambler.ru
Russian Federation, ul. Pushkina 1a, Stavropol, 355009
I. V. Borovlev
North Caucasus Federal University
Author for correspondence.
Email: ivborovlev@rambler.ru
Russian Federation, ul. Pushkina 1a, Stavropol, 355009
O. P. Demidov
North Caucasus Federal University
Email: ivborovlev@rambler.ru
Russian Federation, ul. Pushkina 1a, Stavropol, 355009
E. K. Avakyan
North Caucasus Federal University
Email: ivborovlev@rambler.ru
Russian Federation, ul. Pushkina 1a, Stavropol, 355009
A. A. Borovleva
North Caucasus Federal University
Email: ivborovlev@rambler.ru
Russian Federation, ul. Pushkina 1a, Stavropol, 355009
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