Ni-Mo and Ni-Mo-Co composite catalytic alloys for alkaline water electrolysis

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Abstract

Currently, a large number of studies on alkaline water electrolysis are being carried out with the aim of reducing the specific energy costs for the hydrogen evolution reaction and the oxygen evolution reaction. This work is devoted to the methods of synthesis of highly dispersed composite coating on the surface of nickel foam and the methods of the formation of bi- and ternary catalytic alloys based on molybdenum using electrochemical deposition. During the study of the samples morphological and element-by-element analyses were carried out and the activity indicators of the synthesized highly effective catalytic coatings were obtained.

About the authors

Andrew Alexandrovich Gavrillyuk

Moscow Power Engineering Institute

14, Krasnokazarmennaya St.

Vladimir Nikolaevich Kuleshov

Moscow Power Engineering Institute

14, Krasnokazarmennaya St.

Semyon V. Kurochkin

Moscow Power Engineering Institute

ORCID iD: 0000-0002-3617-6812
14, Krasnokazarmennaya St.

Irina I. Lanskaya

Moscow Power Engineering Institute

14, Krasnokazarmennaya St.

Yaroslav V. Isaev

Moscow Power Engineering Institute

14, Krasnokazarmennaya St.

References

  1. Pengcheng Zhao, Jingang Wang, Wei He, Liming Sun, Yun Li. Alkaline zero gap bipolar water electrolyzer for hydrogen production with independent fluid path // Energy Reports. 2022. Vol. 9, № 10. P. 352-360. https://doi.org/10.1016/j.egyr.2023.05.135
  2. Коровин Н. В., Козлова Н. И., Савельвева О. Н., Лапшина Т. В. Московский ордена Ленина энергетический институт. Авторское свидетельство № 715646 СССР, МПК C25B 11/03. Способ изготовления пористого электрода для электрохимических процессов: № 2558425 ; Заявл. 23.12.77 ; Опубл. 15.02.80 ; Бюль. № 6. 2 с.
  3. Sandhya Shetty, M. Mohamed Jaffer Sadiq, D. Krishna Bhat, A. Chitharanjan Hegde. Electrodeposition and characterization of Ni-Mo alloy as an electrocatalyst for alkaline water electrolysis // Journal of Electroanalytical Chemistry. 2017. Vol. 796. P. 57-65. https://doi.org/10.1016/j.jelechem.2017.05.002
  4. Chonglun Fan, D. L. Piron, P. Paradis. Hydrogen evolution on electrodeposited nickel-cobaltmolybdenum in alkaline water electrolysis // Electrochimica Acta. 1994. Vol. 39, № 18. P. 2715-2722. https://doi.org/10.1016/0013-4686(94)00263-0
  5. Gao M. Y., Yang C., Zhang Q. B., Zeng J. R., Li X. T., Hua Y. X., Xu C. Y., Dong P. Facile electrochemical preparation of self-supported porous Ni-Mo alloy microsphere films as efficient bifunctional electrocatalyst for water splitting // Journal of Materlials Chemistry A. 2017. Iss. 17. P. 5797-5805. https://doi.org/10.1039/C6TA10812A
  6. Huan Liu, Daozhang Liu, Xu Cheng, Zhangsheng Hua, Shiwei He. One-step electrodeposition of Ni-Mo electrode with column-pyramid hierarchical structure for highly-efficient hydrogen evolution // Materials & Design. 2022. Vol. 224. Article number 111427. https://doi.org/10.1016/j.matdes.2022.111427
  7. Qing Han, Shuang Cui, Nianwen Pu, Jianshe Chen, Kuiren Liu, Xujun Wei. A study on pulse plating amorphous Ni-Mo alloy coating used as HER cathde in alkaline medium // International Journal of Hydrogen Energy. 2010. Vol. 35, iss. 11. P. 5194-5201. https://doi.org/10.1016/j.ijhydene.2010.03.093
  8. Beltowska-Legman E., Indyka P. Kinetics of Ni-Mo electrodeposition from Ni-rich citrate baths // Thin Solid Films. 2012. Vol. 520. iss. 6. P. 2046-2051. https://doi.org/10.1016/j.tsf.2011.10.024
  9. Allam M., Benaicha M., Dakhouche A. Electrodeposition and characterization of NiMoW alloy as electrode material for hydrogen evolution in alkaline water electrolysis // International Journal of Hydrogen Energy. 2017. Vol. 43, iss. 6. P. 3394-3405. https://doi.org/10.1016/j.ijhydene.2017.08.012
  10. Jaksic M., Brun J., Johansen B., Tunold R. Some specific potentiodynamic features of nickel electrodes in alkaline aqueous media // International Journal of Hydrogen Energy. 1995. Vol. 20, № 4. P. 265-273. https://doi.org/10.1016/0360-3199(94)E0019-U
  11. Mriappan V., Krishnamoorthy K., Pazhamalai P., Sahoo S., Kim S. Electrodepositied molybdenum selenide sheets on nickel foam as a binder-free electrode for supercapacitor application // Electrochimica Acta. 2018. Vol. 265. P. 514-522. https://doi.org/10.1016/j.electacta.2018.01.075
  12. Кулешов В. Н., Курочкин С. В., Кулешов Н. В., Гаврилюк А. А., Пушкарева И. В., Климова М. А., Григорьева О. Ю. Щелочной электролиз воды с анионообменными мембранами и катализаторами на основе никеля // Электрохимия. 2023. Т. 59, № 11. С. 735-750. https://doi.org/10.31857/S0424857023110105

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