Email this article Transformations of Ethanol on Catalysts Based on Nanoporous Calcium Aluminate–Mayenite (Ca12Al14O33) and Mayenite Doped by Copper
- Authors: Mironova E.Y.1, Ermilova M.M.1, Orekhova N.V.1, Tolkacheva A.S.2,3, Shkerin S.N.2, Yaroslavtsev A.B.1,4
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Affiliations:
- Topchiev Institute of Petrochemical Synthesis
- Institute of High Temperature Electrochemistry, Ural Branch
- Institute of New Materials and Technologies
- Kurnakov Institute of General and Inorganic Chemistry
- Issue: Vol 12, No 11-12 (2017)
- Pages: 597-604
- Section: Article
- URL: https://journal-vniispk.ru/2635-1676/article/view/220266
- DOI: https://doi.org/10.1134/S1995078017060064
- ID: 220266
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Abstract
Catalytic properties of nondoped and copper-doped Mayenite have been studied. During ethanol conversion and ethanol steam reforming, the initial Mayenite and specimens containing 0.58 and 0.92 wt % of copper have been analyzed. All catalysts are active in both processes. The influence of the ethanol/water mole ratio on product distribution has been studied. In the course of experiments, the fact of reversible hydrogen sorption has been detected upon the thermal treatment of catalysts containing copper.
About the authors
E. Yu. Mironova
Topchiev Institute of Petrochemical Synthesis
Author for correspondence.
Email: palukas@ips.ac.ru
Russian Federation, Moscow, 119991
M. M. Ermilova
Topchiev Institute of Petrochemical Synthesis
Email: palukas@ips.ac.ru
Russian Federation, Moscow, 119991
N. V. Orekhova
Topchiev Institute of Petrochemical Synthesis
Email: palukas@ips.ac.ru
Russian Federation, Moscow, 119991
A. S. Tolkacheva
Institute of High Temperature Electrochemistry, Ural Branch; Institute of New Materials and Technologies
Email: palukas@ips.ac.ru
Russian Federation, Yekaterinburg, 620090; Yekaterinburg, 620078
S. N. Shkerin
Institute of High Temperature Electrochemistry, Ural Branch
Email: palukas@ips.ac.ru
Russian Federation, Yekaterinburg, 620090
A. B. Yaroslavtsev
Topchiev Institute of Petrochemical Synthesis; Kurnakov Institute of General and Inorganic Chemistry
Email: palukas@ips.ac.ru
Russian Federation, Moscow, 119991; Moscow, 119991
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