PREPARATION OF NEW HARD ELASTIC POLYMERIC MATERIAL BASED ON ULTRA-HIGH MOLECULAR WEIGHT POLYETHYLENE

О. V. Аrzhakova; Аржакова О. В.; А. Yu. Yarusheva; Ярышева А. Ю.; A. I. Nazarov; Назаров А. И.; А. А. Dolgova; Долгова А. А.; A. L. Volynskii; Волынский А. Л.

doi:10.31857/S2686953522600623

PREPARATION OF NEW HARD ELASTIC POLYMERIC MATERIAL BASED ON ULTRA-HIGH MOLECULAR WEIGHT POLYETHYLENE

Authors: Аrzhakova О.V.¹, Yarusheva А.Y.¹, Nazarov A.I.¹, Dolgova А.А.¹, Volynskii A.L.¹
Affiliations:
1. Lomonosov Moscow State University, Faculty of Chemistry
Issue: Vol 510, No 1 (2023)
Pages: 80-86
Section: PHYSICAL CHEMISTRY
URL: https://journal-vniispk.ru/2686-9535/article/view/135981
DOI: https://doi.org/10.31857/S2686953522600623
EDN: https://elibrary.ru/OVTCHR
ID: 135981

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Abstract
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Abstract

A novel approach for the preparation of hard elastic polymeric material based on ultra-high molecular weight polyethylene via the strategy of crazing of polymers has been proposed. This approach includes the process of deformation of the pristine films of ultra-high molecular weight polyethylene via environmental intercrystallite crazing mechanism and subsequent low-temperature spontaneous strain recovery upon stress relaxation. As a result, the material acquires new properties typical for hard elastic materials: restoration of the porous structure upon secondary loading in air up to ~20 vol. % with pore sizes in the nanometer range (up to 10 nm), high reversibility of deformation (50−85%), the effect of opening and closing pores upon cyclic loading. The mechanism of this phenomenon has been proposed and the areas of practical applications of such mechanoresponsive material have been indicated.

Keywords

ultra-high molecular weight polyethylene, crazing, mesoporous structure, hard elastic polymeric material, mechanoresponsive polymeric materials

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