


Vol 60, No 5-6 (2016)
- Year: 2016
- Articles: 29
- URL: https://journal-vniispk.ru/0026-0894/issue/view/14792
Article
Use of Contemporary Information Technology for Analyzing the Blast Furnace Process
Abstract
Computer implementation of mathematical models, algorithms, and computer programs is given for resolving a set of production problems in the field of blast furnace production introduced into Magnitogorsk Metallurgical Combine. Requirements are considered for the structure and architecture of a computer system for support of solutions adopted for an MES-level Blast Furnace Technologist workstation. A short description is provided for the main model sub-systems, and also assumptions made during mathematical modeling. Use of the systems makes it possible for engineering and production personnel to perform operational analysis of a blast furnace workshop situation, to resolve a number of production problems for controlling blast furnace heat, gas-dynamic, and slag regimes, and also to calculate the optimum blast furnace charge composition, which finally provides an improvement in blast furnace production technical and economic operating indices.



Modeling High-Alloy Chromium-Nickel Alloy Nanostructuring with Treatment by Highly-Concentrated Energy Sources
Abstract
A mathematical model is provided for phase transformation thermodynamics making comprehensive study possible for the equilibrium phase composition of chromium-nickel welded joints at different temperatures. According to the model, with a chromium content of more than 22 wt.% the temperature for the start of intermetallic precipitation exceeds the solidus temperature for Cr–Ni alloy, i.e., in this case precipitation of primary Ni3Al intermetallic is thermodynamically possible. Primary Ni3Ti precipitates are probable with a chromium content of more than 36 wt.%. Model calculations are confirmed by microstructural studies. In order to improve welded joint strength for the alloy in question, slow joint cooling in the range below 1000°C is recommended, depending on welded structure operating temperature, and ageing in the range of intense γ′-phase precipitation, i.e., 900–600°C. The mathematical model developed for phase transformation thermodynamics may be used for studying the phase composition of other chromium-nickel alloys.



Effect of Alloying with Molybdenum and Chromium on Pipe Steel of Strength Category X65 Properties
Abstract
Kinetics of austenite phase transformation in previously deformed steels of different alloy systems during continuous cooling are studied. It is shown that with a basic chemical composition of 0.06% C and 1.55% Mn–Nb–Ti alloying with chromium (0.19%) leads to the formation after cooling of an almost identical microstructure, as also with addition of molybdenum (0.14%), from the point of view of fineness and hardness. An optimum steel alloy system is suggested from an economic point of view that provides the required set of properties for rolled sheet more than 30 mm thick of strength category X65 produced under conditions of the VMZ (Vyksa) sheet rolling complex (5000 mill).



Microstructure and Property Formation for High-Strength Low-Carbon Steels Microalloyed with Titanium and Molybdenum
Abstract
Features of microstructure formation for hot-rolled product of low-carbon steels microalloyed with titanium and molybdenum are studied. The possibility is demonstrated of achieving a high level of mechanical properties due to forming a volumetric system of nanosize complex (Ti, Mo)C carbide precipitates during cooling after hot rolling, including during cooling of a wound coil with γ → α transformation, and also as a result of forming a finely dispersed ferrite structure with increased dislocation density. Conformity of the temperature for the end of rolling and strip winding on a coil with a cooling regime in this temperature range, and also an increase in free titanium content in this steel, are desirable.



Effect of Thermal Action on Low-Carbon and Silicon-Manganese Steel Microstructure and Properties
Abstract
The change in microstructure is considered for silicon-manganese and low-carbon steels under conditions modeling prolonged thermal action. Metal structure and property degradation is revealed. It is shown that prolonged thermal action creates conditions for the occurrence of thermal deformation ageing, the initial stage of recrystallization, and also pearlite spheroidization.



Factors Determining the Level of Mechanical Properties of Chromium Corrosion-Resistant Steels Alloyed with Nitrogen
Abstract
Chromium corrosion-resistant steels alloyed with nitrogen are studied by experiment. It is shown that depending on chemical composition and process parameters the structure of the chromium steels obtained may be martensitic with a minimum residual austenite content, martensitic with a greater content of residual austenite, or three-phase, consisting of martensite, residual austenite, and ferrite. The possibility is demonstrated of increasing steel martensite ductility by forming a specific amount of austenite within the steel structure.



Effect of Chemical Composition and Structure on Mechanical Properties of Low-Alloy Weldable Steels After Thermomechanical Treatment
Abstract
On the basis of analyzing 22 melts of high-strength steel (σ0.2 = 428–886 MPa) of different grades 3–25 mm thick produced within countries of the European Union by thermomechanical rolling technology, the effect of chemical composition and structure on a set of mechanical properties is studied. It is shown that yield strength of high-strength steels is due to titanium, niobium, and vanadium carbonitrides. The contribution of titanium to steel strength is greater than that of niobium by a factor of three, and by a factor of 16.5 for vanadium. An increase in steel yield strength above 750 MPa leads to its inclination towards an increase in impact strength anisotropy coefficient Ka. In the concentration range 0.001–0.08 wt.% Ti, the value of Ka = 1–2 is independent of Ti content, but increases sharply to Ka = 3.8 with a Ti content in steel of 0.09 to 0.14 wt.% giving rise to a requirement for limiting Ti content to not more than 0.08 wt.%. A marked effect of Ti and Al concentration on high-strength steel impact strength is established with entirely ductile failure KCVmax. According to x-ray-spectral analysis data, coarse (with a size of 2.2–2.8 μm) inclusions have a complex structure. During formation, inclusions contain up to 15–17 wt.% Al, and then an outer layer forms upon them having up to 29–42 wt.% Ti.



Production Methods for Increasing Pipe Drawing Tool Life
Abstract
Contact pressure distribution in a die channel during sink drawing of an Al–Mg–Mn alloy system pipe is obtained. Schemes are considered for establishment and the nature of die loading during operation. In order to reduce forces within a grip, sharpening of a workpiece is proposed with a cone angle less than that of the die. The effect of finishing zone length for the first die and entry zone of the second die on magnitude of bending moment on entry of a workpiece into a block of dies with misalignment is studied. Pipe drawing is studied in one and two dies in a DEFORM program. Recommendations are made for improving die life.



Production of Ferrosilicotitanium for Smelting Pipe Steels
Abstract
Research is carried out for preparation of ferrosilicotitanium by self-propagating high-temperature synthesis (SHS) using ferroalloy powders as starting materials. On the basis of data obtained, industrial technology is developed and assimilated for producing ferrosilicotitanium for alloying pipe steels instead of a high percentage ferrotitanium. An industrial test batch is prepared and tests are carried out successfully under Magnitogorsk Metallurgical Combine conditions.



Factory Tests of Temper-Rolling Fluid Volgol-350 on the 2030 Mills at the Novolipetskii Metallurgical Combine
Abstract
are presented from import substitution of Qwerl 275-2 temper-rolling fluid (Quacker Chemical B.V.) by domestic Volgol-350 temper-rolling fluid (VPO Volgokhimneft). A range of methods for evaluating the quality of temper-rolling fluids were developed in the course of testing. Lab studies and industrial testing of limited batches of Volgol-350 fluid made it possible to determine the optimum requirements for protective capacity, attainment of a clean surface on steel strip, and elimination of excessive lubricating properties. Volgol-350 temper-rolling fluid has been used in the production of cold-rolled products at the NLMK since 2006.



Modification of the Surface of Products by Plastic Deformation and Deposition of Functional Coatings*
Abstract
The possibility of using a rotary-disk sectional wire brush has been investigated for the nanostructuring of metal products’ surface layer and the subsequent application of functional coatings. It was established that a nanostructured surface layer with fragment dimensions up to 0.13 μm can be obtained by a percussive-frictional method that is similar to high-rate plastic deformation. The microtopography of specimen surfaces was studied under different processing modes.



Imparting Ductility to a Steel–Aluminum Composite Laminate in Forming Operations
Abstract
One of the major disadvantages of corrosion-inhibiting aluminum coatings on steel is the presence of a brittle intermetallide layer between the steel substrate and aluminum coating. This paper reports results from an investigation of the problem. A manufacturing scheme based on the treatment of such laminated composites by forming operations is proposed.



Filtering Elements of a New Design and Equipment for Their Manufacture
Abstract
Existing designs and manufacturing techniques for filters with a slot-hole structure are analyzed. It is proposed that slotted filter tubes be made by the method of deformational cutting. The method has been realized by through wall slotting of longitudinally corrugated welded metal pipe. Options are discussed for the basic structure of complexes designed to make slot-hole filtering pipes.



Use of Special High-Rigidity Profiles in the Load-Bearing Systems of Tractors and Automobiles at the Magnitogorsk Metallurgical Combine
Abstract
Special reinforced profiles for the load-bearing systems of tractors and automobiles are likely to be in high demand in the future. They provide these systems the required strength and stiffness values, particularly in diagonal torsion. Preliminary tests have shown that the cab of the promising VT-200 tractor could be made from a certain combination of special reinforced profiles made at the Magnitogorsk Metallurgical Combine. In a first approximation, an element of the tractor-cab floor was developed and design studies were carried out. Analyses have shown that the proposed solution provides the required strength properties without increasing the estimated weight or dimensional characteristics while keeping manufacturability and costeffectiveness at acceptable levels.



Simulation of the Consolidation of a Porous Material in a Combined Rolling–Extrusion Process
Abstract
The combined rolling–extrusion of a porous aluminum billet is simulated mathematically using the finite-element method and QFORM V8 software. A three-dimensional problem statement with one plane of symmetry is used. The fields of displacement rates, stresses, temperatures, strains, and density are plotted. It is concluded that the distribution of these parameters is asymmetric about the processing axis. It is revealed that the density achieved in the process is close to that of the compact material.



Improvement of the Efficiency of Hot Strip Rolling with Controlled Coil Cooling
Abstract
Controlled coil cooling (CCC) improves the consumer properties of the entire range of products of continuous hot wide-strip rolling without costly thermal treatment. The CCC process also contributes to the improvement of the efficiency of hot strip rolling by reducing the loan payments due to the reduction of the overall production cycle and recovery of the great quantity of heat accumulated in all hot coils.



Recycling of Electrolyzer Spent Carbon-Graphite Lining with Aluminum Fluoride Regeneration
Abstract
The spent lining of aluminum electrolyzer is one of the most environmentally hazardous wastes of the aluminum industry due to its content of up to 0.2 wt.% cyanide and up to 40 wt.% fluorides. The majority of spent lining is accumulated near aluminum plants in specially equipped landfills, where it can interact with water and air, with formation of toxic compounds and alkaline solutions that could lead to ground water contamination. At the same time, spent lining is of specific value due to presence of fluoride and up to 30 wt.% carbon. Known technology for processing spent lining with preparation of cryolite in operation at some aluminum plants has lost its importance after introduction of dry gas cleaning and a change-over to electrolysis technology using acidic electrolytes. This has led to a substantial reduction of cryolite requirement. Therefore, at present more attention is devoted to technology for producing aluminium fluoride, including from spent lining. This article provides a brief review of known technology for processing aluminum electrolyzer spent lining. Technology is provided for preparing aluminium fluoride product containing fluorine of 55–59 wt.%; thus, there is a reduction in fresh AlF3 consumption of about 4–6 kg/ton Al. Laboratory test results are provided.



Briquetting Metallurgical Lime Screenings and Parameters Making it Possible to Improve Process Efficiency
Abstract
Results are given for roll briquetting of metallurgical lime. Experimental results are obtained in laboratory presses and industrial briquetting units. Dependences are obtained for briquette density on compaction pressure and process productivity with different roll briquetting parameters. Technology and equipment presented in the work for lime briquetting make it possible to prepare high quality briquettes for the metallurgical industry. Results obtained are used in developing production briquetting processes and planning equipment.



MMK Blast Furnace Operation with a High Proportion of Pellets in a Charge. Part 1
Abstract
Results are given for analysis of agglomerate and pellet physicochemical properties. It is shown that with transfer of blast furnace smelting into an operating regime with a high proportion unfluxed pellets in a charge requires changing the main slag regime parameters, and also the furnace charging regime. It is established that due to the difference in agglomerate and pellet physicomechanical properties, and also as a result the high corrosiveness of primary slag obtained using unfluxed pellets, it is necessary to change the regime for material charging into a furnace. With an increase in the proportion of Sokolovo-Sarbaiskii Ore Mining and Processing Combine pellets in Magnitogorsk Metallurgical Combine blast furnace charge, there is a reduction in amount of magnesium in final blast furnace slags. This is accompanied by an increase in molten slag viscosity, a reduction in its sulfur absorbing capacity, and also an increase in the temperature range for iron ore mix melting with an increase in bottom gas pressure drop and limiting melt blast force.






Effect of Treatment Temperature Regimes in a Continuous Annealing Unit on Two-Phase Ferritic-Martensitic Steel Mechanical Properties
Abstract
Features of structure and property formation are studied for cold-rolled product in two-phase ferriticmartensitic steels by modeling heat treatment in a continuous annealing unit (CAU) of six laboratory melts of different chemical composition intended for preparing steels of different strength classes according to EN10338:2013. Steel of some melts, apart from alloying with elements currently used extensively, are additionally alloyed with aluminum. Hot- and cold-rolling processing regimes simulate those used under production conditions. Results of modeling heat treatment in a CAU by different regimes show an increase in strength and a reduction in ductility properties with a reduction in overageing temperature. Rolled product of steel alloyed with aluminum has lower strength properties, ratio of yield to ultimate strengths, but better relative elongation values.



Study and Modeling of Annealing Regimes in Bell Furnaces for Cold-Rolled High-Strength Microalloyed Steels
Abstract
A detailed study is performed on laboratory melted model high-strength steels microalloyed with niobium of features of the change in microstructure, mechanical properties, and excess phase precipitate formation in relation to hot rolling and bell furnace annealing parameters. It is established that an increase in annealing temperature and duration leads to a reduction in the level of mechanical properties and an increase in rolled product grain size. Annealing parameters are found providing optimum steel microstructure fineness for steels hardened during stamping. Proof is obtained for adequacy of the results of laboratory modeling for annealing, and good prospects are demonstrated for adaptation of the regimes developed to industrial conditions.



Increase in Corrosion Resistance in Aqueous Media of Low-Alloy Steel Used as the Main Layer of Corrosion-Resistant Bimetals
Abstract
The article is devoted to a study of corrosion resistance of low-alloy steels, in relation to chemical composition, heat treatment conditions, other steel properties, and heat treatment regimes. The effect of chemical composition, degree of deoxidation, and steel cleanliness with respect to nonmetallic inclusions on steel corrosion resistance is demonstrated, including those that may be used as a main layer in corrosion-resistant bimetals.



The Effect of Quenching Temperature on the Structure and Properties of Alloy Ei437B-VD Blades for a Helicopter Gas Turbine Engine
Abstract
Results are given for a study of the effect of quenching temperature on macro- and microstructure, and mechanical properties of nickel-based superalloy EI437B-VD. It is shown that in order to improve structure stability and mechanical properties of rolled bar and stamped GTE blades made of alloy EI437B-VD, and also to avoid a different grain size, it is necessary to reduce quenching temperature in performing heat treatment from 1080 ± 5°C to 1020 ± 5°C.



Investigation and Choice of Materials for the Electrical Insulation of the Steel Bloom of an Aluminum Electrolyzer
Abstract
The growth of the modern aluminum industry is characterized by a search for methods of increasing the capacity of electrolyzers, reducing emissions into the environment, and reducing energy consumption. In the production of aluminum, the specific electricity consumption can be reduced and current efficiency increased by decreasing the distance between the anode and cathode and at the same time reducing the horizontal currents in the molten aluminum. The horizontal component of the current density can be reduced by placing electrical insulation between the cathode carbon block and the bloom on the section ‘crust boundary – projection of the anode periphery on the bottom block’. Heatproof materials with the following properties are technologically most effective and economical for use as electrical insulation: good adhesion to steel, chemical resistance to cryolite-alumina melt, and quite low ultimate strength in compression. Low strength and stiffness are needed because during thermal expansion of the materials in the bottom block during the period of heating the tank to the working temperature with high resistance to compression there is a risk of the load increasing on the carbon cathode block and cracks forming in it. Moreover, such properties of the material will make it possible to decrease the risk of fracture of the cathode carbon block if the volume of the electric-insulation insert increases as a result of the electrolyte penetrating into it. The results of the investigations of the mechanical properties of some heatproof materials for use as electrical insulation of blooms in aluminum electrolyzers at high temperatures are presented in order to optimize the composition.



Features of Shaimerden Deposit Oxidized Zinc Ore Leaching
Abstract
The object studied is Shaimerden oxidized zinc ore deposit containing zinc, lead, copper, iron, calcium, magnesium, aluminum, manganese and silicon. Chemical and mineralogical composition of the ore are investigated. It is established that ore coarse fraction contains more zinc carbonate and less zinc silicate compared with undersize particles. In addition, ore coarse fraction is richer in residual forms (nontronite, sphalerite) hardly soluble in sulphuric acid solution. Thermodynamic analysis of probable transformations during leaching is carried out, kinetics of coarse fraction and undersize particles of ore leaching is studied, and Pourbaix diagrams are plotted for analysis of processes occurring at a phase interface during leaching of oxidized zinc ore. Studies for stripping oxidized zinc ore are carried out on large (–20+1 mm) and small (–1+0 mm) fractions. Optimum leaching parameters are established for fine and coarse ore fractions: sulfuric acid concentration and process temperature and duration (C(H2SO4) = 150–160 g/liter, temperature 60°C, leaching time 60 min). Dependences are determined for the degree of zinc extraction into solution on sulphuric acid concentration, temperature, and leaching duration for coarse and fine ore factions.



Effect of Contact Melting Regime on Structure and Properties of Coatings of the Copper–Titanium System
Abstract
The effect of temperature and duration of contact melting on composition, structure, and properties of coating of the Cu–Ti system is studied. It is shown that an increase in temperature with short exposures facilitates preparation of a finer structure and an increase in coating hardness. An increase in contact melting duration leads to structural component coagulation and a reduction in coating average hardness values. Equations are obtained for determining processing parameters for explosive welding and hightemperature heating regimes for forming a coating of required thickness and phase composition.



Features of Aluminum Alloy Microplasma Oxidation During Operation in a Polar Pulsating Current Regime
Abstract
Results are given for microplasma oxidation process using a pulsating power source constructed on the basis of semiconductor elements. Features are revealed for microplasma oxidation in silicate electrolyte with performance of the process in a pulsating polar current in an anodic regime with prescribed signal rectangular shape. The dependence of microplasma process depending on aluminum alloy AMg5 surface treatment, and also mechanical properties of oxide coatings obtained on electric current pulse frequency in an object-electrolyte circuit part is demonstrated.



Color Mark Formation on a Metal Surface by a Highly Concentrated Energy Source
Abstract
The results of a study of the influence of the parameters of laser heat-treatment of a metal surface on the formation of the color gamut in the zone of exposure to a laser beam are presented. The prospects for using laser marking of the surface of a metal part can be greatly increased by controlling the color of the applied image. The ‘color’ version of the method of laser marking can be effectively used in the metallurgical industry to protect against counterfeiting of articles made from unique essential alloys used in, for example, the aerospace industry.


