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Vol 74, No 9-10 (2018)

Science for Glass Production

Glass Molding (Review)

Guloyan Y.A.

Abstract

Different methods of molding glass and their physical-chemical and technological particulars are examined. The structural and deformation characteristics of glass-forming melts, forehearth characteristics of glass, and the molding conditions in isothermal and non-isothermal regimes are noted. An expanded classification of molding processes is presented

Glass and Ceramics. 2018;74(9-10):305-315
pages 305-315 views

Effect of Calcium, Barium, and Strontium on the Thermal Properties of Borosilicate Glasses

Eremyashev V.E., Zherebtsov D.A., Osipova L.M., Brazhnikov M.V.

Abstract

The effect of additions of calcium, barium, and strontium oxides on the thermal properties of sodium fluorosilicate glasses was studied by means of differential scanning calorimetry. The data obtained from the thermal studies are compared with the results of structural studies of these glasses, and the factors determining the observed change of vitrification temperature and specific heat are established. The obtained results make it possible to adjust the parameters of synthesis and heat treatment of matrix glass-containing borosilicate materials used for immobilization of radioactive waste.

Glass and Ceramics. 2018;74(9-10):345-348
pages 345-348 views

Glass Ceramics

Particulars of a Reactive Interaction in the Composite Mixture of Glass 0.5MgO · 0.2BaO · 0.3B2O3 – Kaolin

Fomenko G.V., Nosenko A.V., Goleus V.I., Il’chenko N.Y., Amelina A.A.

Abstract

The sequence of formation of the crystalline phases during heat-treatment of composite glass mixtures 0.5MgO · 0.2BaO · 0.3B2O3 – kaolin is determined by means of thermodynamic calculations. It is shown that celsian is the primary crystalline phase and cordierite the secondary phase.

Glass and Ceramics. 2018;74(9-10):316-318
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Science for Ceramic Production

Preparation and Thermal Stability of Nanodisperse Bicomponent Materials in the System SnO2–CeO2

Liberman E.Y., Mikhailichenko A.I., Malysheva T.N., Kon’kova T.V., Kolesnikov V.A.

Abstract

The possibility of formation and the thermal stability of nano-disperse bicomponent materials in the system SnO2–CeO2 were studied. The samples were identified by means of XPA, TEM-HTXPA, and low-temperature adsorption of nitrogen.

Glass and Ceramics. 2018;74(9-10):319-322
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Possibility of Using Dielectric Channels as Deflecting Systems for Controlling Accelerated Electron Beams

Vokhmyanina K.A., Sotnikova V.S., Kaplii A.A., Kubankin A.S., Ivashchuk O.O., Kishchin I.A., Nazhmudinov R.M., Sotnikov A.V.

Abstract

The results of an investigation of the passage of 10-keV electron beam through dielectric channels fabricated from ceramic (zirconium dioxide) and pyroelectric crystals (lithium niobate) are presented. The angle of deflection of the electron beam by the channels was measured as a function of the angle of interaction of the beam with the internal walls of the channels. The obtained results indicate the possible prospects of using dielectric surfaces as effective deflectors of accelerated charged particles.

Glass and Ceramics. 2018;74(9-10):355-357
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Article

Modification of Ceramic by Organosilicon Polymer Capable of Transitioning Into Silicon Carbide

Chukhlanov V.Y., Selivanov O.G., Chukhlanova N.V., Pikalov E.S., Sysoev É.P.

Abstract

The possibility of increasing the strength of ceramic by introducing the ceramic-forming polymer polydimethylsilane into the batch is examined. Upon the introduction of polydimethylsilane into the mix a transition of polydimethylsilane into polycarbosilane is observed in the presence of the catalyst molybdenum chloride and is followed by a transition of polycarbosilane into silicon carbide. It is shown that the introduction of this additive with weight content > 4% increases strength and decreases open porosity.

Glass and Ceramics. 2018;74(9-10):323-325
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Sol-Gel Synthesis by Means Of Eutectic Additives for Silicon Carbide Based Ceramic

Mararakin M.D., Vartanyan M.A., Makarov N.A., Sazhin I.V.

Abstract

Sol-gel synthesis by the eutectic composition method was conducted in the ternary oxide system MgO–Al2O3–Y2O3, used as a sintering additive for silicon oxide based ceramics. Alaboratory method of preparing additives is proposed and the influence of the synthesis temperature on the powder properties is determined.

Glass and Ceramics. 2018;74(9-10):326-328
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Convergence Check of Data from Step-by-Step Experimental-Computational Magnetic Control of Iron Impurities in Raw Materials Using Different Field Sources

Sandulyak A.V., Polismakova M.N., Sandulyak A.A., Sandulyak D.A., Ershova V.A.

Abstract

The mass-operational characteristics of magnetic control of iron impurities in raw materials (silica sand, feldspar, gypsum), following an exponential law both fully and partially (tail section), when an experimental-computational model of control of iron impurities is possible taking account of the appropriate corrections, are analyzed. It is shown for different sources of the field that the results of magnetic control performed with a limited number of operations differ considerably between one another while for an unlimited number of operations (operational-computational method) they remain practically identical even though the form of the mass-operational characteristic changes.

Glass and Ceramics. 2018;74(9-10):332-336
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Methods of Synthesizing Alumomagnesium Spinel Powders for Obtaining Transparent Ceramic (Review)

Senina M.O., Lemeshev D.O., Kolesnikov V.A.

Abstract

The prospects for using optically transparent ceramic made from alumomagnesium spinel are examined. The technologies for synthesizing spinel powders for subsequent use in obtaining transparent ceramic are described.

Glass and Ceramics. 2018;74(9-10):358-363
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Investigation of Cutting Ceramic Stability During Sharpening of Hardened Steel Blanks

Pronin A.I., Myl’nikov V.V., Shchelkunov E.B., Chernyshov E.A.

Abstract

The results of investigations of the stability of VOK-60 cutting ceramic during machining of hardened steel blanks made of No. 45 steel of different hardness 45 HRC and 54 HRC are presented. The stability of the cutting ceramic plate during machining of a harder blank is 41% higher than in machining of a less-hard blank. A microstructural analysis of the damage to the working surface was performed and the mechanism of wear of the cutting plate was determined. The reasons for the more rapid wear of the plate during machining of a less-hard blank were determined.

Glass and Ceramics. 2018;74(9-10):364-366
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Stability of Foam-Silicate Aggregates Against Alkali in Cement

Kazantseva L.K., Seretkin Y.V., Puzanov I.S.

Abstract

The chemical activity with respect to alkali in cement (ASR resistance) for granulated aggregates (Penosital®, classic foam glass, microspheres of fly ash) in aqueous extract from concrete was investigated. The basic conditions for reaching ASR resistance of aggregates such as foam sital and microspheres of fly ash were determined.

Glass and Ceramics. 2018;74(9-10):372-377
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At Enterprises and Institutes

Intermediate Process Control of the Fabrication of a Conducting Layer on the Surface of Nanofibrous Materials

Shcherbakova N.N., Pereshivailov V.K., Perevoznikova Y.V., Sleptsov V.V.

Abstract

Coatings on glass witness samples, making it possible to set the process regimes for deposition, as well as the operational parameters of the setup — working current, voltage, limit and working vacuum as well as the required number of coating layers — were investigated. The measurement of the resistance of metallized coatings on nonwoven materials in definite regimes showed a value from 32 to 11 Ω/cm2, as set by the experimental conditions.

Glass and Ceramics. 2018;74(9-10):329-331
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Prospects for Using Different Types of Transparencies in the Manufacture of Aircraft Canopies (Review)

Mekalina I.V., Yakovlev N.O., Kharitonov G.M., Khitrova O.I.

Abstract

The prospects for using aircraft transparency parts based on silicate, organic, or polycarbonate glasses from the standpoint of strength, the primary sources of loading, and the most vulnerable locations are reviewed. Suggestions for increasing their strength reliability are described.

Glass and Ceramics. 2018;74(9-10):367-371
pages 367-371 views

Biomaterials

Bioactive Ceramics Based on Zirconium, Aluminum, and Titanium Oxides

Medkov M.A., Grishchenko D.N., Nedozorov P.M., Kuryavyi V.G., Rudnev V.S.

Abstract

A method for producing porous ceramic biocompatible with living tissues owing to the introduction of calcium phosphates in the interior of the ceramic was developed on the basis of zirconium, titanium, and aluminum oxides. A bioactive coating is formed directly during the fabrication of the sample. The resulting two-phase ceramic is characterized by developed microrelief. The samples meet the mechanical requirements of implants to be used as bone tissue replacements.

Glass and Ceramics. 2018;74(9-10):337-341
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Investigation of Highly Concentrated Calcium Phosphate Suspensions for Forming Bioceramic with Complex Architecture

Putlyaev V.I., Evdokimov P.V., Filippov Y.Y., Safronova T.V., Tikhonov A.A.

Abstract

The rheological properties of highly concentrated calcium phosphate suspensions for producing bioceramic with complex shape by means of slip casting and 3D-printing were investigated. Macroporous bioceramic with gyroid architecture was prepared by casting water slips into polymer molds with gyroid geometry, which were fabricated by thermal-extrusion and stereolithographic 3D-printing. The limitations of this technology in reproducing fine details as compared with direct 3D-stereolithography of ceramic suspensions are indicated.

Glass and Ceramics. 2018;74(9-10):378-381
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Equipment

Hoppers for Glass-Batch Mixers

Efremenkov V.V.

Abstract

Different designs of hopper assemblies for glass batch mixers are examined. The factors affecting the shape, volume, and number of receiving hoppers for mixers are determined. It is shown that buckets as well as vibratory, auger, and ribbon feeders can be used to unload a batch from the mixing apparatus. Certain variants of rotary vibratory mechanisms used for unloading a mixture of raw materials from the receiving hoppers of batch mixers are presented.

Glass and Ceramics. 2018;74(9-10):349-354
pages 349-354 views