Email this article Synthesis of 4-aryl-1,7-dihydroxyalkane-2,6-diones under aldol reaction conditions
- Authors: Mavrov M.V.1
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Affiliations:
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Issue: Vol 65, No 3 (2016)
- Pages: 714-720
- Section: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/237488
- DOI: https://doi.org/10.1007/s11172-016-1361-8
- ID: 237488
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Abstract
Reactions of 3-hydroxyalkan-2-ones with (hetero)aromatic aldehydes under basic conditions lead to 4-aryl-1,7-dihydroxyalkane-2,6-diones. These products were also synthesized by dismutation of 4-aryl-1-hydroxyalk-3-ene-2-ones. The reactions proceed as tandem retro aldol reactions and the Michael addition.
About the authors
M. V. Mavrov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: anutagig@mail.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
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