Slow large-scale supramolecular structuring as a cause of kinetic anomalies in the liquid-phase oxidation with nitric acid

Аннотация

Isothermal calorimetry, static and dynamic light scattering, and NMR spectroscopy studies provided evidence for slow formation of large associates of solvates in aqueous solutions of nitric acid, which makes it possible to attribute the anomalous kinetic features in the oxidation of acetone to the supramolecular mechanism of the reaction.