Отправить статью по E-mail Slow large-scale supramolecular structuring as a cause of kinetic anomalies in the liquid-phase oxidation with nitric acid
- Авторы: Lagodzinskaya G.V.1, Laptinskaya T.V.2, Kazakov A.I.1, Kurochkina L.S.1, Manelis G.B.1
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Учреждения:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Department of Physics, M. V. Lomonosov Moscow State University
- Выпуск: Том 65, № 4 (2016)
- Страницы: 984-992
- Раздел: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/237787
- DOI: https://doi.org/10.1007/s11172-016-1401-4
- ID: 237787
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Аннотация
Isothermal calorimetry, static and dynamic light scattering, and NMR spectroscopy studies provided evidence for slow formation of large associates of solvates in aqueous solutions of nitric acid, which makes it possible to attribute the anomalous kinetic features in the oxidation of acetone to the supramolecular mechanism of the reaction.
Об авторах
G. Lagodzinskaya
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: gvl@icp.ac.ru
Россия, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
T. Laptinskaya
Department of Physics, M. V. Lomonosov Moscow State University
Email: gvl@icp.ac.ru
Россия, Build. 2, 1 Leninskie Gory, Moscow, 119991
A. Kazakov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: gvl@icp.ac.ru
Россия, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
L. Kurochkina
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: gvl@icp.ac.ru
Россия, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
G. Manelis
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: gvl@icp.ac.ru
Россия, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
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