Slow large-scale supramolecular structuring as a cause of kinetic anomalies in the liquid-phase oxidation with nitric acid


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Isothermal calorimetry, static and dynamic light scattering, and NMR spectroscopy studies provided evidence for slow formation of large associates of solvates in aqueous solutions of nitric acid, which makes it possible to attribute the anomalous kinetic features in the oxidation of acetone to the supramolecular mechanism of the reaction.

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G. Lagodzinskaya

Institute of Problems of Chemical Physics, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: gvl@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

T. Laptinskaya

Department of Physics, M. V. Lomonosov Moscow State University

Email: gvl@icp.ac.ru
俄罗斯联邦, Build. 2, 1 Leninskie Gory, Moscow, 119991

A. Kazakov

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: gvl@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

L. Kurochkina

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: gvl@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

G. Manelis

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: gvl@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

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