Slow large-scale supramolecular structuring as a cause of kinetic anomalies in the liquid-phase oxidation with nitric acid
- 作者: Lagodzinskaya G.V.1, Laptinskaya T.V.2, Kazakov A.I.1, Kurochkina L.S.1, Manelis G.B.1
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隶属关系:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Department of Physics, M. V. Lomonosov Moscow State University
- 期: 卷 65, 编号 4 (2016)
- 页面: 984-992
- 栏目: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/237787
- DOI: https://doi.org/10.1007/s11172-016-1401-4
- ID: 237787
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详细
Isothermal calorimetry, static and dynamic light scattering, and NMR spectroscopy studies provided evidence for slow formation of large associates of solvates in aqueous solutions of nitric acid, which makes it possible to attribute the anomalous kinetic features in the oxidation of acetone to the supramolecular mechanism of the reaction.
作者简介
G. Lagodzinskaya
Institute of Problems of Chemical Physics, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: gvl@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
T. Laptinskaya
Department of Physics, M. V. Lomonosov Moscow State University
Email: gvl@icp.ac.ru
俄罗斯联邦, Build. 2, 1 Leninskie Gory, Moscow, 119991
A. Kazakov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: gvl@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
L. Kurochkina
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: gvl@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
G. Manelis
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: gvl@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
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