Chemospecific synthesis of 2-acetoxyindole-3-carbonitriles catalyzed by Cu(acac)2
- Авторы: Mo S.1, Tu J.1, Xu J.1
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Учреждения:
- State Key Laboratory of Chemical Engineering Resource, Department of Organic Chemistry, Faculty of Science, Beijing University of Chemical Technology
- Выпуск: Том 65, № 7 (2016)
- Страницы: 1773-1778
- Раздел: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/238557
- DOI: https://doi.org/10.1007/s11172-016-1509-6
- ID: 238557
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Аннотация
A chemospecific one-pot synthesis of easily isolable 2-acetoxyindole-3-carbonitriles was described. The intermediate 2-oxindole-3-carbonitriles successfully prepared from 2-cyano diazoacetanilides without isolation were treated with acetyl chloride and triethylamine to give 2-acetoxyindole-3-carbonitriles. The developed one-pot approach showed broad substrate scope.
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Shanyan Mo
State Key Laboratory of Chemical Engineering Resource, Department of Organic Chemistry, Faculty of Science, Beijing University of Chemical Technology
Email: jxxu@mail.buct.edu.cn
Китай, Beijing, 100029
Jianzhuo Tu
State Key Laboratory of Chemical Engineering Resource, Department of Organic Chemistry, Faculty of Science, Beijing University of Chemical Technology
Email: jxxu@mail.buct.edu.cn
Китай, Beijing, 100029
Jiaxi Xu
State Key Laboratory of Chemical Engineering Resource, Department of Organic Chemistry, Faculty of Science, Beijing University of Chemical Technology
Автор, ответственный за переписку.
Email: jxxu@mail.buct.edu.cn
Китай, Beijing, 100029
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