Enviar artigo por via de e-mail Synthesis of new chiral amidophosphite ligands and their application in hydrogenation of benzodiazepinones and enamides
- Autores: Sokolovskaya M.V.1, Lyubimov S.E.1, Davankov V.A.1
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Afiliações:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Edição: Volume 66, Nº 7 (2017)
- Páginas: 1213-1216
- Seção: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/240926
- DOI: https://doi.org/10.1007/s11172-017-1875-8
- ID: 240926
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Resumo
New chiral amidophosphites were synthesized and tested in the Ir-catalyzed hydrogenation of 4-substituted 1,3-dihydro-2H-1,5-benzodiazepin-2-ones and Rh-catalyzed hydrogenation of dehydro amino acid derivatives. The triphenylphosphine additive can considerably increase the enantioselectivity of both processes.
Sobre autores
M. Sokolovskaya
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: lssp452@mail.ru
Rússia, 28 ul. Vavilova, Moscow, 119991
S. Lyubimov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Autor responsável pela correspondência
Email: lssp452@mail.ru
Rússia, 28 ul. Vavilova, Moscow, 119991
V. Davankov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: lssp452@mail.ru
Rússia, 28 ul. Vavilova, Moscow, 119991
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