Vol 118, No 3-4 (2023): ТЕМАТИЧЕСКИЙ БЛОК: ФУНДАМЕНТАЛЬНЫЕ НАУЧНЫЕ ИССЛЕДОВАНИЯ В ОБЛАСТИ ЕСТЕСТВЕННЫХ НАУК
- Year: 2023
- Articles: 9
- URL: https://journal-vniispk.ru/1605-8070/issue/view/19910
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Description:
Настоящий выпуск журнала «Вестник РФФИ» особенный – он не является тематическим, как предыдущие, поскольку посвящен 30-летнему юбилею конкурса «инициативных проектов фундаментальных научных исследований», проводимых во всех областях знаний. Это – самый первый и наиболее известный конкурс РФФИ, который получил код «а» и сокращенное название – конкурс «а».
Full Issue
THEMED ISSUE EDITOR’S COLUMN
About the Editor of the Themed Section Academician Vladislav Panchenko



Abstract of the Themed Section



THEMED SECTION: FUNDAMENTAL SCIENTIFIC RESEARCH IN THE FIELD OF NATURAL SCIENCES
Study of Weather and Climate Predictability at Seasonal Time Scales with Climate Model of INM RAS
Abstract
Prediction system of seasonal weather and climate anomalies is developed on the basis of INM RAS climate model. The model includes block of atmospheric dynamics with surface and soil model, block of ocean and sea ice dynamics, and aerosol block. Initial states were generated as anomalies of atmospheric, oceanic and ice states derived from reanalysis added to model climatology. Simulation of weather anomalies in December–February and June–August, 1980–2014 was considered. It is shown that model is capable to reproduce anomalies of winter and summer seasons, including anomalies associated with North Atlantic Oscillation (NAO), Pacific North American Oscillation (PNA). The quality of seasonal forecasts with developed prediction system is close to the quality of other present day seasonal prediction systems. Operative simulations of weather anomalies in June–August, 2022, are considered. It is possible to use successfully the prediction system in operative regime.



Long-Term Impact of Landfills and Municipal Solid Waste Landfills on the Transformation of Groundwater Chemistry
Abstract
An integrated approach to assessing the impact of landfills of municipal solid waste on the transformation of the chemical composition of groundwater is considered. Examples are given to study the regularities of pollutant transfer into leachate as well as changes in the intensity and scale of their leakage into groundwater depending on the stages of organic compound degradation in the landfill body, features of changes in the hydrogeochemical conditions in the post-reclamation period are considered. An ecological and geochemical assessment of the condition and role of unsaturated zone sediments as a secondary source of groundwater pollution at the sites of landfills in the Moscow region is carried out. An example of forecasting of pollution transport in the landfill body and groundwater by using numerical modeling of moisture and mass transport processes in the unsaturated zone and groundwater flow and transport processes modeling is described for the "Dubna Pravoberezhnaya" landfill.



Preparation and Study of Fe and Ni Containing Composite Materials Based on Zeolite H-ZSM-5 as Membranes for Hydrogen Purification
Abstract
The separation of complex hydrogen-containing gas mixtures in order to obtain technical and high-purity hydrogen is an important scientific and technical task that determines the possibility of further systematic development of the "green" economy. The article presents the results of a study of Fe and Ni containing membranes based on zeolite H-ZSM-5 and aluminum oxide, used to purify hydrogen from carbon monoxide, carbon dioxide and nitrogen. Mono and bimetallic Fe and Ni containing membranes were obtained by hot pressing aluminum oxide and H-ZSM-5 zeolite with subsequent secondary growth of the zeolite on the membrane surface, adsorption and reduction of active metals.
Synthesized mono and bimetallic samples Al2O3-ZSM-5-Fe, Al2O3-ZSM-5-Ni and Al2O3-ZSM-5-Fe-Ni with different content of active metals were investigated by various physicochemical methods including low-temperature nitrogen adsorption, chemical adsorption of ammonia, hydrogen, X-ray fluorescence analysis. The bimetallic sample Al2O3-ZSM-5-c-Fe-3%-Ni-2% has higher selectivity in the separation of hydrogen from complex mixtures compared to the results given in the literature. The high selectivity of the above membrane may be due to the possibility of a higher rate of hydrogen adsorption and its migration over the surface of bimetallic particles.



Molecular Genetic Analysis of Cases of Hearing Loss in Evenks and Evens of Yakutia
Abstract
living in Yakutia. It was found that in 45.5% of cases the genetic etiology of hearing impairment in Evenks and Evens is associated with the prevalence of three forms of deafness – DFNB103, DFNB1A and MTRNR1 – caused by pathogenic variants of the CLIC5, GJB2 and MT-RNR1 genes, respectively. Genetic and epidemiological analysis showed that the territorial prevalence of DFNB103, DFNB1A and MTRNR1 in Yakutia was 1 in 82 973, with local accumulation in the Eveno-Bytantaisky national district (1 in 264). Clinical and genealogical analysis of cases of hearing loss in this national district indicated the family causes of the accumulation of identified forms of hearing loss, which is probably due to the endogamy of the marriage structure of this population of Eastern Siberia.



RNA-Chromatin Interactions. The Data Analysis.
Abstract
This article reviews approaches to the study of data on RNA-chromatin interactions. Data sources and the data processing methods and protocol we developed are described. The RNA-Chrom database (https://rnachrom2.bioinf.fbb.msu.ru) is also described. Some features of the data are reviewed and future plans are presented.



Sentiment Frames for Russian: Creation, Testing, Use
Abstract
In this paper we describe the lexicon RuSentiFrames for Russian, where predicate words and expressions are collected and linked to so-called sentiment frames conveying several types of presupposed information on attitudes and effects. We applied the created frames in the task of extracting attitudes from a large mass-media news collection of texts in Russian. Experiments have shown that the use of RuAttitudes for fine-tuning of BERT-like models leads to an increase in the quality of extracting the sentiment of relations.



On the Issue of Thermal Stability of Metallization Systems and Contacts of Ultra-Large Integrated Circuits
Abstract
The work is devoted to the development of a method for diagnosing thermal overloads of metallization systems of ultra-large integrated circuits. The considered metallization systems with a thickness of 0.5 μm with sublayers with a thickness of 0.1 μm (the width of the Al film was 7–70 μm) were exposed to single rectangular current pulses with a duration of no more than 600 μs and an amplitude of up to 8·1010 A/m2.Temperature fields were modeled using experimental oscillograms, melting processes in multilayer thin-film systems were analyzed. It was found that when exposed to a single rectangular current pulse with a duration not exceeding 80 μs and an energy of 85 mJ, the processes of melting of a metal film are the priority process of destruction of the structure. An increase in the pulse duration (τ>80 μs) changes the priority of thermal degradation, and contact melting becomes the main mechanism. It is shown that the presence of titanium and silicon oxide sublayers increases the thermal "load" on the metallization layers and can lead to a decrease in the critical current density. Using the example of the Al–Ti–Si system, it was revealed that isothermal annealing leads to an improvement in the heat-conducting properties of the system and an increase in critical current densities.


