Vol 26, No 3 (2024)

TECHNOLOGY

Assembly of threaded and adhesive-threaded joints with the application of ultrasonic vibrations

Sukhov A.V., Sundukov S.K., Fatyukhin D.S.

Abstract

Introduction. The main problem in the use of threaded joints is the reduction of the preliminary force under the influence of workloads, which contribute to stress relaxation in the joint elements. The main directions of intensifying assembly operations in order to improve the performance properties of a threaded joint are improving the design of joints, using adhesive compositions that, after polymerization, prevent unscrewing. One of the ways to modernize the assembly is the use of ultrasonic vibrations, which makes it possible to influence the distribution of forces arising during assembly, as well as to process treat the adhesive to improve its properties. Research methodology. Experimental studies were carried out in three stages. At the first stage, the influence of shear ultrasonic vibrations on the threaded joint assembly process was assessed. As a complex indicator that determines the effectiveness of the impact, a relative unscrewing torque is proposed, which takes into account the change in the tightening torque under vibration conditions and the increase in the unscrewing torque after assembly. At the second stage, studies were carried out on the effect of ultrasonic treatment on the properties of epoxy adhesive in the liquid (viscosity) and polymerized state (submicrostructure, microhardness, shear stress). At the third stage, the adhesive threaded joint was assembled with the simultaneous addition of adhesive and the application of vibrations. Results and discussion. The application of shear ultrasonic vibrations with an amplitude from 5 to 9 μm leads to an increase in the relative unscrewing torque by 1.5 times, which is associated with the creation of an additional force that promotes tightening and a decrease in friction, which acquires the characteristics of quasi-viscous. At the same time, ultrasound increases the uniformity of load distribution along the thread turns, which is confirmed by the absence of its deformation at a higher tightening torque. Ultrasonic treatment of the adhesive at amplitudes of 8...12 μm leads to a decrease in viscosity to 70–80 % and an increase in strength to 24 %, which is explained by the action of cavitation and acoustic flows. The assembly of an adhesive threaded joint at vibration amplitude of 9 μm combines effects that promote tightening and increase the properties of the adhesive. As a result, such a connection has a relative unscrewing torque 1.95 times greater compared to the control one.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):6-23
pages 6-23 views

Thermomechanical rolling in well casing production (research review)

Baraboshkin K.A., Adigamov R.R., Yusupov V.S., Kozhevnikova I.A., Karlina A.I.

Abstract

Introduction. The modern oil and gas industry requires the development of high strength materials for well casing. Changes in rolled steel production technologies are one of the urgent tasks. Reducing the cost of high quality steel well casing is becoming a major challenge for the oil and gas industry. Multiphase microstructures containing acicular ferrite or an acicular ferrite-dominated phase exhibit good complex properties in HSLA steels. This paper focuses on the results obtained using modern methods of thermomechanical rolling. Results and discussion. This work analyzes the characteristics of thermomechanical rolling technologies and its impact on the microstructure of rolled steel for well casing. It is shown that predicting mechanical properties based on the microstructural characteristics of steel is complicated due to the large number of parameters involved. This requires an optimal microstructure of the steel. A satisfactory microstructure depends on several factors, such as chemical composition, hot work processing, and accelerated cooling. Alloying elements have a complex effect on the properties of steel, and alloying additives are usually introduced into the steel composition. From a metallurgical point of view, the choice of alloying elements and the metallurgical process can greatly influence the resulting microstructure. Conclusion. This review reports the most representative study regarding thermomechanical rolling technologies and microstructural factors in well casing steels. It includes a summary of the most important process variables, material properties, regulatory guidelines, and microstructural and mechanical properties of the metal for well casing production. This review is intended to benefit readers from a variety of backgrounds, from non-metal forming or materials scientists to various industrial application specialists and researchers.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):24-51
pages 24-51 views

Modeling and optimization of roller burnishing of Al6061-T6 process for minimum surface roughness, better microhardness and roundness

Dwivedi R., Somatkar A., Chinchanikar S.

Abstract

Introduction. Roller burnishing is one of the most common methods of improving the surface quality of parts, wear resistance, microhardness, and corrosion resistance. The process involves compressing and smoothing the workpiece using the pressure of a hardened roller. It is often used to improve part performance and lifespan in sectors including automotive, aerospace, and medical equipment manufacturing. The literature reviewed shows that the roller burnishing process effectively improves the overall surface quality and hardness of the workpiece. In addition, roller burnishing is considered as an affordable method to enhance the functionality and robustness of machined parts by reducing the likelihood of surface defects such as like scratches and cracks. However, very few studies have been reported on the modeling and optimization of roller burnishing of Al6061-T6 for minimum surface roughness, better microhardness, and roundness. The methods of investigation. In the current work, roller burnishing of Al6061-T6 is modeled and optimized for superior microhardness, roundness, and minimal surface roughness. Under dry-cutting conditions, the performance of roller burnishing of Al6061 specimens is assessed in terms of process factors such as cutting speed, feed, and number of passes. Mathematical models to predict the surface roughness, microhardness, and deviation in roundness are developed based on the experimental results. Results and Discussion. The coefficient of correlation for the developed models is found to be close to 0.9, which indicates that it can be reliably used to predict and optimize the roller burnishing of the Al6061-T6. According to this study, the use of the following cutting parameters leads to the lowest variation in roundness (4.282 µm), the better microhardness (119.2 Hv), and the lowest surface roughness (0.802 µm): cutting speed 344 rpm, feed 0.25 mm/rpm and four passes. Further, the study reveals that increasing the number of passes (beyond four) does not significantly improve the surface roughness or microhardness. However, it does lead to a slight increase in the roundness deviation. Therefore, in order to achieve optimal results, it is recommended to use a maximum of four passes during roller burnishing of Al6061 specimens under dry cutting conditions. These results imply that roller burnishing can effectively improve the overall quality and hardness of the workpiece surface. In addition, roller burnishing is considered as an affordable method to increase the functionality and robustness of machined parts by reducing the likelihood of surface defects like scratches and cracks.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):52-65
pages 52-65 views

Experimental studies of rail grinding modes using a new high-speed electric drive

Ilinykh A.S., Pikalov A.S., Miloradovich V.K., Galay M.S.

Abstract

Introduction. The operation of rail grinding is used in railway transport as a preventive measure for the formation and development of defects of contact and fatigue origin, wave wear and deformation of transverse profile rails. Currently, JSC Kaluga Plant “Remputmash”, together with Siberian State University, is developing a new high-capacity rail train named PHSP 2.0. PHSP 2.0 is 3.5 times more productive than existing analogues. PHSP 2.0 technology is based on high-speed rail grinding, which requires cutting speed up to 100 m/s. The rotation of grinding wheel is controlled by an electric motor. Todaу there is no industrial electric drive capable of implementing the required characteristics (7,000 rpm, 45 kW, 60 H·m). The aim of this work is to study the modes of rail grinding using a new high-speed electric grinding wheel containing a synchronous electric motor with permanent magnets and frequency converter, which feeds motor with an AC voltage with an increased frequency and provides control of the grinding wheel rotation speed. Research methods. In order to obtain results of operation of the new electric drive in conditions as close as possible to real-world operating modes and the possibility of implementing high-speed grinding technology, research tests were carried out on a specially designed rail-welding machine. The measurement of grinding wheel speed was carried out by the laser tachometer “Megeon 18005”; the assessment of metal removal after mechanical processing was carried out by the profiler rail PR-03; the pressure in pneumatic system was measured with pressure transducers of measuring units VDH 100I-DY1,6-111-0.5. Results and discussion. According to research results, new high-speed electric drive was found to have increased performance due to increased performance and ability to adjust speed of grinding wheel, thus providing the necessary removal of rail head metal with a significant increase in the speed of rail train movement.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):66-78
pages 66-78 views

Assessment of the possibility of resistance butt welding of pipes made of heat-resistant steel 0.15C-5Cr-Mo

Karlina Y.I., Konyukhov V.Y., Oparina T.A.

Abstract

Introduction. Cr-Mo steels are used in high-temperature and high-pressure applications, including critical components of modern supercritical and ultra-supercritical thermal power plants. Due to its unique ability to withstand high temperatures and pressures, these steels are also used in critical components of fast breeder nuclear reactors. The heterogeneity of the microstructure and mechanical properties throughout the welded joint is a decisive factor leading to a decrease in its performance and premature failure. Post-weld heat treatment is the main method for improving mechanical properties. However, the mechanism for the evolution of mechanical properties associated with heterogeneous microstructure after heat treatment remains unclear, which complicates the design of the heat treatment process and a comprehensive assessment of its effect. The purpose of the work is to assess the possibility of the resistance butt welding method of welding pipes made of 0.15C-5Cr-Mo steel, to select technological parameters for resistance butt welding of pipes to obtain high mechanical properties. Research methods. The experiments were carried out on a resistance butt welding machine MSO-201N. Mechanical tests for static tension, chemical composition analysis and metallographic studies were carried out. Results and discussion. Technological parameters of resistance butt welding of pipes, changed in the course of our research, show that upsetting pressure and spark allowance affect the final strength properties of the welded joint. Based on the results of metallographic studies, the following features of the evolution of the microstructure can be noted. A noticeable decrease in the content of primary coarsened ferrite is observed in the structure of the weld after tempering. The use of post-weld heat treatment made it possible to reduce the hardness in the welded joint to the level of regulatory requirements. Results presented. The effect of heat treatment on mechanical properties is analyzed based on a comparison of heat treatment modes: stress relief annealing and normalization + tempering in terms of improving mechanical properties during tensile tests. The results show that after tempering, the evolution of mechanical properties in each sub-zone of the welded joint is sequential, i.e., hardness and tensile strength decrease and toughness increases. It is noteworthy that the most significant increase in toughness is observed in the weld zone, primarily due to a significant decrease in the presence of hypoeutectoid ferrite.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):79-93
pages 79-93 views

Product life cycle: machining processes monitoring and vibroacoustic signals filtering

Gimadeev M.R., Stelmakov V.A., Shelenok E.A.

Abstract

Introduction. In modern manufacturing, the product life cycle comprises various stages, from conception to disposal. Among these stages, machining plays a significant role, as it directly influences the durability and functionality of the finished product. With increasing competition and the need to reduce production costs, optimizing machining processes has become a crucial task. Traditionally, conservative technological approaches have been used to ensure processing quality. However, this often leads to decreased productivity and higher costs. Modern monitoring and diagnostic techniques can significantly improve process control, particularly through tool condition monitoring. The subject. This paper discusses the stages of the product life cycle and emphasizes the importance of monitoring machining processes. It explores the potential of using vibroacoustic signals to continuously monitor equipment and product conditions. Special attention is paid to the use of vibroacoustic signals for diagnostics and quality control. Modern approaches to filtering these signals, including the use of the fast Fourier transform and various window functions, are analyzed in order to improve the accuracy of the analysis and identify potential defects. The purpose of this work is to develop an algorithm for an online monitoring system that will monitor the condition of cutting tools based on the creation of a digital shadow using a vibroacoustic complex. The main tasks to be solved are to establish the ranges of applicability of frequency response of acoustic signals and optimal window functions, as well as to establish the relationship between the degree of wear on the cutting tool and the results of vibration diagnostics and surface roughness. The methods and technologies for filtering vibroacoustic signals and their application in real–world production settings are discussed. Special attention is given to the role of digital twins in integrating monitoring and filtering data, allowing for the creation of a virtual model of a product to predict its behavior and optimize processes throughout the life cycle. A comparison of various monitoring methods and technologies is conducted, as well as an analysis of practical examples of digital twin implementation in production processes and its impact on improved control. Results and discussion are presented, identifying current research and practical advancements, while also proposing existing challenges and promising areas for future research in the fields of monitoring, signal filtering, and the use of digital twins in mechanical manufacturing.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):94-113
pages 94-113 views

EQUIPMENT. INSTRUMENTS

Information properties of frequency characteristics of dynamic cutting systems in the diagnosis of tool wear

Zakovorotny V.L., Gvindjiliya V.E., Kislov K.V.

Abstract

Introduction. One of the directions for increasing the efficiency of cutting is related to the creation of tool wear diagnostic systems. Algorithms and devices have been developed that evaluate wear based on analysis of the vibroacoustic emission signal. These algorithms, as a rule, do not reveal the nature of its formation and the reasons for the change as wear develops. Subject. The paper is devoted to the analysis of the reasons for changes in vibration properties with the development of tool wear. The aim of the work is to study the changes in the frequency characteristics of a dynamic cutting system caused by the development of wear, and to build diagnostic information models on this basis, as well as its use in industry. Method and methodology. The results of mathematical simulation of a perturbed dynamic cutting system are presented, in which the observed vibration sequences are a consequence of disturbances transformed by a dynamic system, the parameters of which depend on wear. Two frequency ranges are considered. Results and discussions. The first range includes frequencies that lie within the bandwidth of the instrument subsystem. The second is outside of it. In the first frequency range, it has been analytically and experimentally proven that the development of wear leads to fundamental changes in the frequency properties of the cutting system as a converter of disturbances into tool vibrations. There is a shift in the natural frequencies of the oscillatory circuits formed by the cutting system, a decrease in its quality factor, and as wear develops, some identified features of the vibration spectra appear, including the ratio of the low-frequency and high-frequency parts of the spectrum, etc. In the second frequency range, a model of force emission in the form of a random pulse sequence is considered and wear is displayed in it. The results of studying the coherence function between the forces acting on the tool and vibrational displacement are presented. Information models of wear are proposed, an example of an information model of wear and the results of its use in industry are given.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):114-134
pages 114-134 views

Features of the use of tool electrodes manufactured by additive technologies in electrical discharge machining of products

Ablyaz T.R., Blokhin V.B., Shlykov E.S., Muratov K.R., Osinnikov I.V.

Abstract

Introduction. The paper presents the results of a study of the use of a tool electrode (TE), manufactured by selective laser alloying from MS1 maraging steel powder for copy-piercing electrical discharge machining (EDM). Purpose of the work: experimental study of the features of the use of additively manufactured TE in the EDM of critical products. Research methods. The specimens were prepared using a ReaLizer SLM 50 system. The starting material was spherical MS1 powder with an average particle size of 30 μm. To test the modes and select a TE sample with the least number of surface defects, four manufacturing modes were tested, and the best TE sample was selected for further research. The EDM was carried out on EMT Smart CNC equipment in a dielectric oil environment. The specimens were installed in a clamp with straight polarity and were used as TE; a 0.12C-18Сr-10Ni-Тi steel plate served as the workpiece electrode. The study was conducted using a factorial experiment (type 23) with a central design. The input data of the factorial experiment is the current I (A), voltage U (W), pulse on time Ton (μs). The output parameters were the roughness parameter Ra and tool electrode wear γ. The roughness parameter Ra was measured using a Mahr Perthometer S2. Results and discussion. TE samples were made from MS1 powder using the SLS method; the highest quality TE sample No. 4 was selected for EDM. Empirical equations are obtained that describe the relationship between the roughness parameter Ra and tool electrode wear γ, depending on the EDM modes. At the minimum mode with a current I = 4 A and a voltage U = 50 V, the tool electrode wear is γ = 0.0063875 g. The maximum tool electrode wear is γ = 0.13938 g with a current I = 8 A and a voltage U = 50 V. It is established that at a constant pulse on time Ton = 75 μs, the smallest roughness Ra = 2.83 μm is obtained at a current of I = 4 A and a voltage U = 100 V, and the maximum roughness is Ra = 4.1568 μm at I = 8 A and U = 100 V.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):135-148
pages 135-148 views

Patterns of reverse-polarity plasma torches wear during cutting of thick rolled sheets

Sidorov E.A., Grinenko A.V., Chumaevsky A.V., Panfilov A.O., Knyazhev E.O., Nikolaeva A.V., Cheremnov A.M., Rubtsov V.E., Utyaganova V.R., Osipovich K.S., Kolubaev E.A.

Abstract

The introduction describes the features of the process of plasma cutting of various metals and alloys using reverse-polarity plasma torches with and the features of cutting thick sheets. The purpose of the work is to study the wear process of plasma torches operating on reverse polarity current when cutting thick rolled sheets of aluminum and titanium alloys. Research methods include optical and scanning electron microscopy, filming of the cutting process and visual inspection of plasma torch elements after receiving specimens. Results and discussion. The section shows the appearance of the main working elements of the plasma torch after cutting in various modes, which led to both stable and gradual wear and to catastrophic failure of the plasma torch. The results of structural studies of the main characteristic zones of nozzles and electrodes after cutting are presented. The studies carried out made it possible to establish the main reasons for the failure of the working elements reverse-polarity plasma torches. The causes of catastrophic failure of plasma torches include failure to maintain the gap between the nozzle and the electrode and melting of the channel of gas supply into the discharge chamber. The wear of nozzles and electrodes in a stable mode can be intensified due to abnormal operation of the starting arc, the presence of manufacturing inaccuracies and excess gas pressure. In conclusion, the main conclusions based on the results of the research are formulated. The process of wear of electrodes, nozzles and body elements of plasma torches during operation at high electric arc power values is described.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):149-162
pages 149-162 views

MATERIAL SCIENCE

Corrosion properties of CuAl9Mn2/ER 321 composites formed by dual-wire-feed electron beam additive manufacturing

Semin V.O., Panfilov A.O., Utyaganova V.R., Vorontsov A.V., Zykova A.P.

Abstract

Introduction. The development of novel materials based on copper alloys and stainless steel, as well as the determination of the optimal parameters for its processing make it possible to expand the area of its implementation, increase efficiency and service life of tools and constructions. The load-bearing parts of marine equipment (bearing constructions, piston cylinders, pumps, valves, gears, rotary instruments, etc.), made of austenitic steels or aluminum bronze, are in direct contact with sea water, so the problem of increasing its corrosion resistance in the presence of strong oxidizing agents (Cl–, F– anions) is relevant. One of the advanced and actively researched methods for producing copper/steel composites is additive manufacturing that allow fabricating complex parts through layer-by-layer growth. In particular, the synthesis of composites based on aluminum bronze and steel can be realized by wire-feed electron beam additive manufacturing. In order to implement composite materials produced via additive technologies in a humid (marine) climate, it is necessary to ensure not only high strength, but also corrosion properties. The purpose of this work is to study the corrosion resistance of composites, based on aluminum bronze CuAl9Mn2 and stainless steel ER 321 produced by dual-wire-feed electron beam additive manufacturing. Research methods. Examination of the surface of CuAl9Mn2/ER 321 composites before and after corrosion tests was carried out by methods of voltammetry and electrochemical impedance spectroscopy using a potentiostat-galvanostat. Results and discussion. Using a complex of electrochemical methods, it is revealed that the developed composites with a volume fraction of steel ≥ 25% demonstrate a significant decrease in anodic current densities and a simultaneous increase in charge transfer resistance. Composites with a steel content of 75 vol. % are characterized by the highest corrosion properties in 3.5 wt. % NaCl solution, which is referred to a reduction in corrosion rate by 9.5 times compared to aluminum bronze. It is shown that the main processes occurring on the surface of the composites (CuAl9Mn2 + ER 321) are anodic oxidation of copper and iron, leading to the formation of corrosion products — Cu2O and FeCl2.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):163-178
pages 163-178 views

Investigation of hardness behavior in aluminum matrix composites reinforced with coconut shell ash and red mud using Taguchi analysis

Dewangan R., Sharma B.P., Sharma S.S.

Abstract

Introduction: in present scenario, light and high strength aluminium metal matrix composite are extensively used due to its high mechanical and tribological properties. Aluminium metal matrix composite reinforced with ceramic and industrial waste can customize its mechanical-chemical behavior. The purpose of the work: to create an aluminum matrix composite material using ceramic (primary) and industrial (secondary) waste represented by red mud and coconut shell ash, respectively. The mass fraction of the strengthening phase varied from 5 to 12.5 wt. % respectively with the residual mass percentage of the aluminum alloy. Method of investigation: nine specimens of composite materials were prepared by stir casting. Stirring was carried out at a speed of 50 to 100 rpm for 20 minutes at a temperature of 800 °C. Result and Discussion: the hardness behavior of the aluminum metal matrix composite was studied at an indentation load of 10, 15 and 20 kN. Taguchi method with L27 orthogonal array was selected to conduct analysis of variance (ANOVA) and regression analysis by selecting the mass percentage of red mud and mass percentage of coconut shell ash. The indentation load was used as an input parameter, and the hardness behavior was taken as an output parameter. The signal-to-noise ratio, response rank table, contour plot, and normal probability plot are investigated and it is found that hardness values improve with the addition of both reinforcing components and indenter load. The results show that the hardness value varies from 33.34 HB to 53.44 HB, and the effect of red mud mass percentage is more significant than the indenter load and coconut shell ash mass percentage.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):179-191
pages 179-191 views

The effect of technological parameters on the microstructure and properties of the AlSiMg alloy obtained by selective laser melting

Saprykina N.A., Saprykin A.A., Sharkeev Y.P., Ibragimov E.A.

Abstract

Introduction. The development of additive technologies is aimed at the synthesis of new powder compositions for selective laser melting plants, the study of the effect of mode parameters on the stable quality of products. The purpose of this work is to study the effect of the scanning strategy on the microstructure, elemental composition, porosity and density of specimens obtained by selective laser melting from non-spherical powders (Al — 91 wt. %, Si — 8 wt. %, Mg — 1 wt. %), subjected to special preparation to determine the optimal conditions for selective laser melting. The research methods are methods of X-ray diffraction and X-ray phase analysis, transmission electron microscopy. The paper examines specimens formed using four different scanning strategies. Results and discussions. A promising aluminum alloy AlSi8Mg is developed for selective laser melting. The material has good manufacturability and low powder cost. The technological parameters of melting make it possible to form a thin structure with a low level of porosity. The mechanism of influence of the scanning strategy on porosity, surface morphology, relative density and microstructure is investigated. A specimen from the AlSi8Mg powder composition with a high relative density of 99.97 % is produced by selective laser melting with an energy density of 200 J/mm3, a specimen scanning circuit when the direction of laser movement changes by an angle of 90° each odd layer. It is proved that the density of the AlSiMg alloy depends on the scanning strategy used. The calculated density of the specimen was 2.5 g/cm3, which corresponds to the density of silumin. Analysis of SEM images and maps of the distribution of elements (Al, Mg, Si) of the specimens showed that different specimen formation strategies do not affect the nature of silicon distribution. A unique grain structure is observed in the resulting AlSi8Mg alloy. The melt pool consists of small grains along the border and large grains in the center. The formation of fine grains is explained by the addition of Si and the high cooling rate during selective laser melting.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):192-207
pages 192-207 views

Methods of synchrotron radiation monochromatization (research review)

Burdilov A.A., Dovzhenko G.D., Bataev I.A., Bataev A.A.

Abstract

The paper presents an analysis of studies related to the monochromatization of X-ray radiation (XR) at synchrotron radiation sources. A review of monochromators based on of X-ray diffraction on crystals is given, and the peculiarities of their technical realization are considered. The ideas about monochromators which include multilayer structures are examined. The authors also study technical problems arising during designing devices and its possible solutions. Introduction. The possibilities of using X-rays in scientific research are described. The high efficiency of synchrotron radiation sources is noted, and its characterization is given. Elementary information about diffraction of X-rays. The paper describes the properties of X-ray radiation and the possibilities of its using while studying various materials. Degree of monochromaticity. The degree of monochromaticity is an important characteristic of the synchrotron radiation (SR). Depending on the width of the wavelength band, “white”, “pink” and monochromatic beams are distinguished. Monochromators based on multilayer structures are used to obtain “pink” beams. Monochromatic radiation is formed using monocrystals. When conducting experiments with “white” beams, the monochromator is not used. The authors also describe the factors that violate the ideal fulfillment of the Wolf-Bragg condition and affect the degree of monochromaticity (heat, vibration). The reflectivity values at different beam grazing angles are noted to have different widths. Monochromators based on multilayer structures. Periodic structures combining thin layers of two heterogeneous materials make it possible to obtain “pink” beams. The wavelength bandwidth of such devices is one or two orders of magnitude greater than that of monochromators using crystals as optical elements. Configurations and geometry of optical elements. There are two types of X-ray diffraction on a crystal: Bragg and Laue diffraction. Bragg diffraction refers to reflective geometry, Laue diffraction is based on the passage of beams through the crystal. The section provides examples of monochromators with different configurations of crystals and X-ray mirrors. The arrangement of optical elements in a monochromator plays an important role in the geometry of the beam path. When designing monochromators, it is necessary to take into account the methods of fixation and orientation of the rotation axes of optical elements. Examples of monochromators with different configurations of crystals and X-ray mirrors are given. Focusing monochromators. It is possible to provide sagittal and meridional types of deformation by bending the optical element of the monochromator. Due to the curved crystal surface the beam is not only monochromatized but also subjected to focusing. Modern focusing monochromators are equipped with adaptivity elements allowing it to change the radius of curvature of the optical element. Examples of practical realization of such monochromators are presented. Thermal load of SR on optical elements. The SR is characterized by high brightness and a wide spectrum of emitted wavelengths. While operating optical elements of SR stations absorb a large amount of thermal power. The problems of heat dissipation have a fundamental influence on the quality of synchrotron radiation monochromatization. Additional information about monochromators. Examples of special design solutions for monochromators are given. Conclusion. The design of monochromators is relevant to the synchrotron radiation source 4+ “SKIF” under construction in Novosibirsk.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):208-233
pages 208-233 views

Wear resistance and corrosion behavior of Cu-Ti coatings in SBF solution

Burkov A.A., Dvornik M.I., Kulik M.A., Bytsura A.Y.

Abstract

Introduction. Currently, titanium and its alloys have become the most popular metal implantable biomaterials. However, the main disadvantage of titanium alloys is low wear resistance due to high viscosity. It is known that copper-titanium coatings effectively improve the antibacterial properties of titanium alloy and at the same time increase its wear resistance. Purpose of the work is to study the effects of a solution simulating body fluid on corrosion properties, friction coefficient and the wear of copper-titanium coatings obtained by electrospark deposition method of the Ti-6Al-4V alloy. Method. A non-localized electrode consisting of copper and titanium granules in various ratios was used to form copper-titanium coatings on a titanium alloy by electrospark deposition. The structure of the coatings was examined using a DRON-7 X-ray diffractometer in Cu-Kα radiation and an X-max 80 energy dispersive spectrometer. The antibacterial activity of the deposited Cu-Ti coatings was studied on a non-pathogenic gram-negative culture of Escherichia coli. Polarization tests in SBF solution were carried out using a P-40X potentiostat with an impedance measurement module. The metal content in the SBF solution after immersion of the samples was measured using an ICP-MS 2000 mass spectrometer. The tribological characteristics of the coatings according to the ASTM G99-17 standard using the “ball-on-disk” scheme with sliding friction in the SBF solution at loads of 10 and 25 N were examined. Results and discussions. It is shown that the bactericidal activity of Cu-Ti coated samples to a non-pathogenic culture of Escherichia coli increased monotonously with an increase in copper content. With copper concentration increasing, the corrosion current density of the coatings increased from 3.455 to 17.570 μA/cm2. It is shown that the SBF solution accelerates the wear of a titanium alloy many times over due to its interaction with the electrolyte via the oxidative wear mechanism. The use of Cu-Ti coatings allows reducing the friction coefficient and greatly decreasing the wear of Ti-6Al-4V alloy in the presence of an electrolyte.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):234-249
pages 234-249 views

Structural features and tribological properties of multilayer high-temperature plasma coatings

Pugacheva N.B., Bykova T.M., Sirosh V.A., Makarov A.V.

Abstract

Introduction. Multilayer high-temperature coatings obtained using plasma spraying, are studied. The combination of layers of different chemical and phase compositions made it possible to increase wear resistance by 1.5–2.0 times. The purpose of this work is to study the influence of the chemical composition of sprayed coatings on the phase composition, structure, micromechanical and tribological characteristics under conditions of dry sliding friction of surface layers. Materials and methods of research. Coatings A and B consist of sequentially sprayed layers. The first and second layers were sprayed in a reducing atmosphere: the first layer was a heat-resistant self-fluxing powder of two systems: 1Fe-Cr-Si-Mn-B-C for coating A and 2 – Fe-Ni-Si-Mn-B-C for coating B; the second layer was a mixture of self-fluxing powder with iron powder in a 1:1 ratio. The third layer was obtained by spraying iron powder in an oxidizing atmosphere to form a metal oxide coating. To create a layer of scale on the surface, coated specimens were subjected to high-temperature annealing at a temperature of 1,000 ?. The chemical composition and nature of the distribution of elements over the thickness of the coatings were determined by micro-X-ray spectral analysis using a TWSCAN scanning electron microscope with an Oxford energy-dispersive attachment. Microhardness and micromechanical properties were studied using an instrumental microhardness tester of the Fischerscope HM2000 XYm system at a load of 0.980 N. Determination of tribological properties was carried out on a laboratory installation using the “finger-disc” scheme at loads of 30, 75, 100 and 130 N. To measure roughness parameters and obtain 3-D profilometry of surfaces after testing, a non-contact profilometer-profiler Optical profiling system Veeco WYKO NT 1100 was used. Results and discussion. Metallographic studies have shown that the formed multilayer coatings consist of an internal metal layer and an external oxide layer with a total thickness of the entire coating up to 800–850 μm. It is established that the first sprayed layer has the highest level of microhardness, which is due to the high-volume fraction of the strengthening phases contained in it (~ 95 %). It is shown that the coating A has increased wear resistance, which is expressed by minimal weight loss (~ 1.5 times less than that of the coating of the coatimg B), the friction coefficient was f = 0.3 for coating A and f = 0.4 for coating B. The study of wear surfaces has shown that for all selected test loads under sliding friction conditions, the coating of both compositions was preserved, even at a maximum load of 130 N.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):250-266
pages 250-266 views

Characterizing the mechanical behavior of eco-friendly hybrid polymer composites with jute and Sida cordifolia fibers

Sharma B.P., Dewangan R., Sharma S.S.

Abstract

Introduction. Recognition of the medicinal properties of plants is an integral part of traditional Indian health systems such as Unani, Siddha, Naturopathy and Ayurveda. Among others, Sida cordifolia, a member of the Malvaceae family, is especially celebrated in Ayurvedic medicine for its outstanding chemical properties. This plant grows in the subtropical and tropical climate of India and symbolizes the global shift towards more environmentally friendly materials. Given the rising environmental concerns, there is an increased demand for biodegradable and renewable resources for industrial applications, especially for reinforcing polymer matrices with natural fibers. The purpose of this study is to investigate the effectiveness of Sida cordifolia fibers combined with jute for reinforcing polylactic acid (PLA) composites. This highlights its potential to improve both environmental quality and mechanical properties of materials. Materials and method. The study involved the fabrication of four different composite specimens: : a solely 4-layered jute fiber mat, untreated Sida cordifolia fibers combined with a 4-layered jute mat, and Sida cordifolia fibers treated with benzoylation combined with a 4-layered jute mat. These composites were subjected to mechanical testing focusing on tensile strength and flexural strength. Its microstructural analysis was also carried out. Results and discussion. The results show that benzoylation-treated Sida cordifolia fibers exhibit significantly higher strength compared to its untreated counterparts. At the same time, an increase in the proportion of Sida cordifolia fibers in composites while maintaining a constant total mass correlates with an increase in the strength of the materials. These results indicate that Sida cordifolia and jute fiber-reinforced PLA composites can provide a competitive, environmentally friendly alternative to synthetic fiber-reinforced composites in a variety of industrial applications. In conclusion, treated natural fibers like Sida cordifolia can significantly improve the mechanical properties of polymer composites, supporting its use as environmentally friendly, high-performance materials in a variety of industries. This research not only promotes the use of natural fibers for commercial applications, but also contributes to the larger goal of sustainable materials science.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):267-285
pages 267-285 views

Fine structure features of Ni-Al coatings obtained by high velocity atmospheric plasma spraying

Kornienko E.E., Gulyaev I.P., Smirnov A.I., Plotnikova N.V., Kuzmin V.I., Golovakhin V.V., Tambovtsev A.S., Tyryshkin P.A., Sergachev D.V.

Abstract

Introduction. Development of Ni-Al intermetallic compounds is one of the priority directions of modern machine building. Due to such characteristics as high heat resistance, high temperature strength, and low density, nickel aluminides are used as functional coatings in the aerospace industry. The main methods of Ni-Al coating surfacing are High-Velocity Oxygen-Fuel and High-Velocity Air-Fuel spraying (HVOF and HVAF), atmospheric plasma spraying (APS) and its modification such as High-Velocity Atmospheric Plasma spraying (HV-APS) which provides non-equilibrium cooling conditions. Since there are eight different intermetallic compounds, as well as martensite transformation, Ni-Al coatings is quite interesting to study. The work purpose is to study the features of the martensitic structure in HV-APS coatings, and also to establish the effect of heating temperature on its decomposition. Materials and methods. Ni-Al coatings were surfaced onto a low-carbon steel substrate using the HV-APS method. Studies of the fine structure of the coatings were carried out using transmission electron microscopy (TEM). In addition, the influence heating temperature on structural transformations of the coatings was analyzed. Results and discussion. Two types of particles are formed in HV-APS coatings: with a dendritic and granular structure. The most part of HV-APS coatings consists of particles with a two-phase grain structure (NiхAl1-х and γ'-Ni3Al grains). Only NiхAl1-x grains undergo martensitic transformation at cooling. Martensite in large grains (sizes greater than 500 nm) has a lamellar structure, while small grains are completely transformed into one martensite plate. In addition, the coatings contain grains in which martensite plates (NiхAl1-х) and β-phases alternated. It is shown the behavior of martensitic plates at colliding with each other, as well as with the γ′-Ni3Al grain. Heating up to 400 °C contribute the begins of martensite decomposition in individual grains with the release of a secondary phase; after heating up to 600 °C all martensite dissolves.
Obrabotka Metallov / Metal Working and Material Science. 2024;26(3):286-297
pages 286-297 views

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