


Vol 10, No 2 (2016)
- Year: 2016
- Articles: 37
- URL: https://journal-vniispk.ru/1027-4510/issue/view/11769
Article
Estimation of the SEM beam diameter by video-signal curves from a trapezoidal structure: 1. Simulation experiment
Abstract
An experiment is performed to determine the electron beam diameter using a comparison of a video signal curve from a relief structure and the one calculated based on a simplified model of curve formation. Rather than the use of an experimental curve for comparison, this model experiment suggests the use of a curve calculated from the data on electron scattering in substrate by the Monte Carlo method. The comparison results revealed the difference between the calculated diameter value and the value of diameter of a model incident beam. It appeared that the parameters of the relief structure and the electron beam affected the calculated diameter values; as a result, these values can vary by several hundred percent in some cases.



Resonant excitation and spatial distribution of fluorescent X-rays at the output of polycapillary structures
Abstract
Experimental and theoretical studies of the angular X-ray-intensity distribution are performed at the output of microchannel plates under the condition that monochromatic radiation is incident on the microcapillary walls at grazing angles. The primary-radiation angles and energies at which a synchrotronradiation beam excites fluorescent X-rays propagating through polycapillary structures are determined. In the case of X-rays passing through microcapillaries, the fine structure of their spectra is investigated at energies corresponding to the anomalous dispersion region of the SiL2, 3 and OK absorption edges. Theoretical calculations are carried out using a model involving a transition layer on the microchannel surface.



Peculiarities of the initial stage of growth of niobium-based nanostructures on a Si(111)-7 × 7 surface
Abstract
The initial stage of growth of nanoislands prepared by thermal deposition of niobium on the reconstructed surface of Si(111)-7 × 7 in ultrahigh vacuum is experimentally investigated. The morphological and electrophysical properties of niobium-based nanostructures are studied by means of low-temperature scanning tunneling microscopy and spectroscopy. It is found that upon the deposition of niobium on a substrate at room temperature, clusters and nanoislands are formed on the silicon surface, having a characteristic lateral size of 10 nm with the metallic type of tunneling conductivity at low temperatures. Upon the deposition of niobium on a heated substrate, quasi-one-dimensional (1D) and quasi-two-dimensional (2D) structures with typical lateral dimensions of up to 200 nm and three-dimensional pyramidal islands with semiconducting type of tunneling conductivity at low temperatures are formed.



In-vitro dissolution and structural and electrokinetic characteristics of titanium-oxynitride coatings formed via reactive magnetron sputtering
Abstract
The results of investigation into the structure and in-vitro dissolution of titanium-oxynitride coatings deposited via reactive magnetron sputtering are presented. Data on the electrostatic and ζ surface potentials enable estimation of their contribution to adsorption processes and coating dissolution in vitro. Sample cultivation in a solution simulating the composition of the inorganic part of human blood plasma leads to surface mineralization, reduces the value and sign of the surface potential, and alters the surface wettability. The coating prevents the transition of iron ions into a solution and does not induce the calcification of an artificial surface.



Giant magnetoresistance of strong magnet–polymer heterostructures with a wide band gap
Abstract
We present the results of studying the effect of a weak external magnetic field on the conductivity of heterostructures containing a wide-gap polymer layer. A set of experiments is singled out for switching the metal–dielectric conductivity, controlled by a weak magnetic field. Evidence of the reliability and repeatability of key experiments are reviewed, and the effect of possible artifacts on switching of the conductivity in the heterostructures under study is discussed.



Simulation of ferromagnetic resonance in a rectangular microstrip
Abstract
The results of the micromagnetic simulation of spectra and the spatial distribution of microwave magnetization oscillations in a rectangular ferromagnetic strip are discussed. It is shown that resonance oscillations have a complex spatial structure which is the composition of quasiuniform precession, longitudinal spin-wave resonance, and localized edge modes.



On the cryocooler-based cooling of Josephson microchips fabricated from cuprate superconductors for use in voltage standards
Abstract
The features of the cooling of arrays of Josephson junctions fabricated from cuprate superconductors, as well as their interaction with microwave radiation during treatment in a closed-cycle cryocooler, are investigated. Estimation of microchip heating sources is carried out by measuring the current–voltage characteristics (IVCs) of the Josephson junctions. On the developed the developed experimental setup, Shapiro steps with a voltage of about 25 mV are obtained on the IVCs of the structure exposed to microwave radiation at a frequency of 75 GHz.



Influence of the magnetization-distribution nonuniformity on the sensitivity of anisotropic magnetoresistive sensors
Abstract
The specific features of numerical calculation of the magnetization-reversal process in thin-film components with large linear dimensions and a complex topology in relation to magnetoresistive transducers (sensors) are considered. The calculated value of the sensor sensitivity obtained within the framework of a uniform and micromagnetic magnetization-reversal model is compared with experimental data. Calculations of the magnetization-reversal process within the framework of the micromagnetic model show the positive effect of edge magnetization pinning which is manifested in the mutual compensation of current and magnetization- distribution nonuniformities; it can be used to enhance the sensitivity of anisotropic magnetoresistive (AMR) sensors.



Cyclotron dynamics of electron wave packets in topological insulators in an external magnetic field
Abstract
The evolution of electron wave packets formed from surface states in topological insulators located in an external magnetic field is studied. The electron and spin densities of the wave packets under consideration are calculated analytically and are visualized. The influence of the main characteristics of the wave packets (the spin polarization) on the splitting and the change in their forms with time is considered.



Microwave impedance of a tunnel junction in the theory of a near-field microscope with atomic resolution
Abstract
A theory is constructed for a near-field microwave microscope operating under tunneling breakdown between a probe and a conducting sample. Its informative characteristics are determined by the probe impedance, which is formed from the capacitive impedance Zp of the near-field probe–sample interaction and tunnel junction impedance Zt. A technique whereby the impedance Zp is calculated using coaxial geometry of the probe is developed. Some properties of the impedance Zt defined via the developed theory and published experimental data are investigated.



On the structural features of influenza A nucleoprotein particles from small-angle X-ray scattering data
Abstract
The structure of ribonucleic particles of influenza A virus of the A/California/07/09pdm strain is investigated by transmission electron microscopy and small-angle X-ray scattering. The small-angle X-ray scattering data obtained at room temperature correspond to previously reported data of ribonucleic particles of this virus. At higher temperatures, noticeable changes in the morphology of ribonucleic complexes are observed.



Small-angle approximation and Oswald–Kasper–Gaukler theory of electron reflection from solids
Abstract
It is shown that the description of the process of electron ref lection from the surface of a solid in the small-angle approximation using the invariant embedding method is completely equivalent to Oswald–Kasper–Gaukler theory. The small-angle approximation is generalized to problems of the determination of the contributions of k-fold inelastic scattering to the energy spectrum of ref lected electrons. The theory is tested by comparing it with the results of other authors and with the data of exact calculations.



Study of multilayer carbon nanotubes subjected to the impact of a nanosecond high-energy ion beam
Abstract
The impact of a nanosecond high-energy ion beam on the structure and morphology of multilayer carbon nanotubes and their ensembles is studied using transmission electron microscopy and scanning electron microscopy. It is shown that ion-beam irradiation leads to a decrease in the outer diameters of carbon nanotubes, which is related to the destruction of their outer layers. In addition, the secondary growth of carbon nanotubes with smaller diameters and the growth of bulblike formations, inside which structures with interplanar distances that are close to those of nanodiamond are fixed, are observed.



On the thermal oxidation of VxOy–InP heterostructures formed by the centrifugation of vanadium(V) oxide gel
Abstract
The optimal mode for the application of a nanoscale layer of vanadium-pentoxide gel on the surface of indium phosphide by centrifugation is determined via spectroscopic ellipsometry and atomic-force microscopy. By oxidizing the formed VxOy—InP heterostructures, films are obtained with a grain structure, with the height of the relief not exceeding 70 nm. The presence of incompletely oxidized chemostimulator components (VO2, V2O3) in the films and the presence of InVO4, which binds the V2O5 chemostimulator and thereby blocks the regeneration cycle of V+5 ↔ V+4, suggest implementation of the transit mechanism of the chemostimulated oxidation of indium phosphide. The data of spectroscopic ellipsometry indicate incomplete kinetic blocking of the diffusion of indium into the films upon oxidation.



Kinetics of the formation of oxide nanostructures on n-Si in the potentiostatic mode of water anodization
Abstract
The results of studies of the morphological properties of an oxide film obtained by the anodic oxidation of a n-Si(100) single-crystal silicon wafer in distilled water in the potentiostatic mode are presented. Irrespective of the value of the applied potential and the anodic treatment time, the oxide coating is always formed as separate islands, interconnected by a thin layer of barrier oxide, the thickness of which is adjusted by the pH value of an alkaline solution (pH > 7) produced in a limited area of local oxidation.



Crystallization kinetics of Al86Ni8Ho6 amorphous alloy
Abstract
We investigate the processes of crystallization and determined the structure and thermal properties of Al86Ni8Ho6 amorphous alloy in a wide temperature range. A three-stage nature of the crystallization process upon heating to a temperature of 700 K is found. According to data of high-temperature X-ray diffraction analysis, the crystallization of an Al86Ni8Ho6 amorphous ribbon is rather complex: aluminum crystallites grow in the amorphous phase to a temperature of 470 K, a Ho3Ni5Al19 phase is formed above 563 K, and a HoAl3 phase appears above 598 K. The phases of Ho3Ni5Al19 and HoAl3 are retained up to a temperature of 723 K. A three-stage kinetic model of the crystallization process with the reaction sequence is proposed based on calculations by multivariate nonlinear regression. The values of the total activation energy for each crystallization stage reach 239, 378, and 247 kJ/mol.



First geochemical data on loose sediments in the Kan-i-Gut cave mine (Central Asia) by synchrotron radiation XRF analysis
Abstract
The elemental composition of loose sediments in the Kan-i-Gut cave mine located in the foothills of the Turkestan range (Kyrgyzstan) is determined by X-ray fluorescence analysis with the use of synchrotron radiation. The samples of loose sediments are selected at different points in the cave, from the entrance to the lowest horizon. The first geochemical data on residual loose sediments in the Kan-i-Gut cave mine are obtained. They allow detailed study of the poorly studied migration of chemical elements in karstic cavities and its specific conditions, which can remain unchanged for a long time.



Peculiarities of the interaction of polycrystalline aluminum with aqueous solutions of gallium
Abstract
We study the effect of gallium-containing aqueous solutions on polycrystalline aluminum. The procedure for kinetic studies of the selected system is described. It is found that in the reaction of polycrystalline aluminum with gallium-containing aqueous solutions, gallium penetrates along the aluminum grain boundaries, which, upon the application of external stress, leads to failure of the sample. It is found that gallium can penetrate along the aluminum grain boundaries both in the liquid and solid state; the rates of penetration of gallium in the liquid and solid states are determined.



Neutron-diffraction study of the crystal structure of BaTiO3 ferroelectric doped with iron
Abstract
The crystal structure of iron-doped barium titanate BaTi1–xFexO3 is studied by neutron diffraction in the range of 0 ≤ x ≤ 0.12. At low concentrations of iron, x < 0.01, and at room temperature, these compounds have a polar structure with tetragonal symmetry with space group P4mm. The temperature of the transition of the tetragonal ferroelectric phase into the cubic paraelectric phase with space group Pm\(\bar 3\)m for an iron concentration of x = 0.01 is 390 K (for pure BaTiO3, it is 410 K). At an iron concentration of x = 0.07, the crystal structure of the studied compounds varies, and it is described by the centrosymmetric hexagonal space group P63/mmc. The structural parameters of various phases of compound BaTi1–xFexO3 are determined from the experimental data.



Influence of field ionization on the efficiency of neutron generation
Abstract
The results of experiments on neutron generation caused by nanosecond discharges in a deuterium medium are presented. The experiments are performed using two types of potential electrodes (anodes). One of them is fabricated from steel foil, and the other is composed of tungsten wires with split ends. In both cases, a deuterium-saturated zirconium plate is employed as a flat grounded cathode. With a tungsten anode, deuterium ions generated by field ionization are demonstrated to constitute the determining part of ions involved in the acceleration process and the neutron yield arising from the reaction 2H(d, n)3He is about four times greater than that inherent to the steel-foil anode. In this case, the maximum neutron yield is 1.2 × 104 neutron/ shot, and the duration of neutron emission from the cathode is 1.5 ns.



Radiation effects in high-temperature composite superconductors
Abstract
We investigate how irradiation with high-energy ions (167-MeV 132Xe27+, 107-MeV 84Kr17+, and 48-MeV 40Ar8+) and 2.5-MeV protons affects the critical parameters of high-temperature superconductor tapes based on YBa2Cu3O7–x and GdBa2Cu3O7–x compounds. The ion ranges in the multilayer structures under study and the thermal regimes of the irradiated samples are calculated using SRIM and thermal-peak models. The calculated results make it possible to estimate the size of radiation-induced defects which serve as the pinning centers of Abrikosov vortices. The performed investigations enable us to reveal that, in the irradiated structures, an increase in the critical current, improvement in the adhesion between the superconducting layer and the substrate, and a reduction in internal stresses are observed under exposure to low levels of Ar- and Kr-ion irradiation. The critical current and the critical temperature decrease at higher fluences and, finally, the phenomenon of superconductivity disappears if the fluence continues to increase. In the case of 2.5-MeV proton irradiation, the radiation resistance of the GdBa2Cu3O7–x samples is found to be higher than that of the YBa2Cu3O7–x tapes.






Classical molecular dynamics simulation of the interaction of hydrogen with defects in tungsten
Abstract
The interaction of interstitial hydrogen (H) with dislocations and point defects in tungsten (W) is studied via numerical simulation within the framework of classical molecular dynamics (MD). Two alternative models are considered to describe the interatomic interactions: the embedded-atom method (EAM) and the bond-saturation model (the bond-order potential (BOP)). The calculated results are compared with data obtained via ab initio quantum-mechanical simulation. The potential developed recently within the framework of the EAM model demonstrated better agreement with the ab initio results than the BOP one. Molecular- statics calculations showed that hydrogen atoms are attracted by the dislocation core in both cases of screw and edge dislocations. The classical MD simulation of hydrogen diffusion in the vicinity of the edge dislocation demonstrated one-dimensional migration along the dislocation line.



Investigation of the heat resistance of zirconia coatings generated by microarc oxidation
Abstract
The heat resistance and thermal conductivity of zirconia coatings with a thickness of ∼200 μm, obtained on zirconium by microarc oxidation, are experimentally investigated. Exposure to nitrogen plasma during thermal tests (temperatures up to 2000°C) results in an increase in the thermal conductivity of the coatings. This is associated with structural changes in the coatings, detected by scanning electron microscopy and X-ray diffraction analysis.



Influence of surface corrugation on the sputtering of carbon materials under high-fluence ion bombardment
Abstract
The results of experimental and computer-based studies of the sputtering and erosion of carbonmaterial surfaces under high-fluence irradiation with 30-keV Ar+ ions at various angles of ion incidence are given. The irradiation of highly oriented pyrolytic graphite (HOPG) and polyacrylonitrile fibers of carbon–carbon composites, which are characterized by surface corrugation, is considered. A model is proposed for taking into account the influence of parameters of symmetric corrugation on the characteristics of sputtering of the irradiated materials. Calculation shows that taking experimental values of the corrugation slopes into account allows one to explain the angular dependence of the sputtering yield of HOPG. It is found that the pronounced (about two times) suppression of sputtering within the range of incidence angles of 60°–80° is connected with the rear (relative to the ion beam) faces of the corrugation being obscured. Unlike the case of the normal incidence of ions, the sputtering yield at large incidence angles decreases as the corrugation period increases due to blocking of the sputtering of the rear and neighboring faces of microrelief elements.



Ion energy losses during the charge-exchange process
Abstract
A method for calculating ion energy losses during the charge-exchange process is proposed. It is established that the contribution of the charge-exchange process to inelastic energy losses for ions with nuclear charges of Z = 5–10 is significant and reaches 15% for certain ions in the energy interval of 30 to 100 keV/nucleon. If a gas target is replaced with a solid one, the ion energy losses during the charge-exchange processes decrease.



On the influence of a high-power ion beam on thin polymer layers deposited onto dielectric substrates
Abstract
The effect of a nanosecond high-power ion beam on thin polymer layers of chlorinated polyvinyl chloride and polymethyl methacrylate containing ferrocene as an additive is investigated. Arrays of carbon nanofibers with a characteristic diameter of 30–160 nm and lengths of up to 15 m are formed on the surface of the chlorinated polyvinyl chloride. The same effect on polymethyl-methacrylate layers leads to intense cavitation of the surface layer. The possible mechanisms of the formation of carbon nanofibers in chlorinated polyvinyl chloride with ferrocene additive under the action of a high power ion beam are discussed.



Local structure of titanium nitride-based coatings
Abstract
The fine structure of X-ray absorption spectra near the K edge and the extended fine structure of X-ray absorption for titanium, copper, and chromium in nanocrystalline coatings based on titanium nitride doped with copper, chromium, and silicon are experimentally studied. The samples are prepared by the evaporation of composite cathodes using the vacuum arc plasma-assisted method. The parameters of the local environment of titanium, copper, and chromium atoms in the structures of the samples under study are calculated. It is established that the presence of a copper impurity in the coating of no more than 12% in amount leads to a slight increase in the Ti–N distance in comparison with the titanium sample, whereas doping with silicon leads, on the contrary, to a decrease in the bond length. The measurement results for the K absorption edges of copper and chromium confirm that the doping elements are concentrated at the edges of the growing titanium-nitride crystallite and determine its size, which corresponds to the sizes of the coherent-scattering region of 40–50 nm.



Propagation of 10-keV electrons through tapered glass macrocapillaries
Abstract
A series of experiments is carried out to study the passage of electrons with an energy of 10 keV through glass macrocapillaries of tapered shape with an input—output diameter ratio of 1 : 10 and 1 : 5. Experiments are performed for different tilt angles of the capillaries with respect to the incident-beam axis. The results demonstrate a significant increase in the current density of a beam passed through the capillaries.



Chemical composition and atomic structure of the surface of copper–manganese alloy modified with oxygen ions
Abstract
The regularities of the formation of the chemical composition of thin surface layers of Cu–Mn alloy under irradiation with oxygen ions in the pulse-periodic mode with different parameters of exposure are investigated by X-ray photoelectron spectroscopy (XPS). We study the distribution patterns and chemical state of the alloy elements in the ion-implanted layers, depending on the dose and energy of irradiation. It is found that with increasing irradiation dose, the alloy components are redistributed in the surface layers, and increasing ion energy leads to decomposition of the initial solid solution.



Modification of YBa2Cu3O7–δ thin films by ion implantation
Abstract
The formation of a topological structure in thin films of the high-temperature superconductor YBa2Cu3O7–δ (YBCO) using ion implantation is studied. The crystal structure and electrical properties of the initial film and the formed insulating regions are investigated. The critical temperature and critical current are measured for microbridges with a width of 3–50 μm fabricated by ion implantation. The results indicate the effectiveness of the ion-implantation method for manufacturing topological structures in YBCO films.



Modeling of cathode sputtering in a low-current gas discharge in a mixture of argon with mercury vapor
Abstract
The energy spectra of ion fluxes bombarding the surface of the cathode are calculated for the case of low-current discharge in an argon–mercury mixture, in which the mercury density is several orders of magnitude lower than the argon density and depends on temperature. The effective rates of tungsten-cathode sputtering by ions of both mixture components and the flux densities of cathode-material atoms sputtered by them are found as functions of the reduced electric-field strength in the discharge gap. It is shown that, at a low mercury content in the mixture, the intensities of cathode sputtering by mercury and argon ions can be comparable in magnitude.



On some problems of modeling the distributions of minority charge carriers generated by an electron beam in a semiconductor material
Abstract
The results of estimating different projection approximation schemes (a modified least-squares method and the Galerkin and Ritz methods) are presented. They are used to simulate the distribution of minority charge carriers, which is observed as a result of the diffusion of minority charge carriers generated by a broad electron beam in a homogeneous semiconductor material. Certain computational features of the implementation of the considered methods are considered.



Modification of MIS structures by electron irradiation and high-field electron injection
Abstract
The change in the charge state of metal–insulator–semiconductor (MIS) structures with a two-layer silicon-dioxide–phosphosilicate-glass gate insulator upon their modification under electron irradiation and high-field electron injection is studied. A thin glass film is formed by doping a thermal SiO2 film formed on the surface of a silicon wafer with phosphorus. It is found that the negative charge accumulated in a thin film of phosphosilicate glass during high-field tunneling electron injection or electron irradiation can be used to adjust the threshold voltage and to increase the charge stability and the breakdown voltage of MIS devices. It is shown that MIS structures need to be annealed at a temperature of approximately 200°C to obtain high thermal-field stability after modification of their charge state by the electron injection or electron irradiation. It is found that the use of a two-layer silicon-dioxide–phosphosilicate-glass gate dielectric increases the average value of the charge injected into the insulator to breakdown and decreases the amount of defect structures.



Cermets as a versatile artificial material for the fabrication of cooled microbolometers for the microwave range
Abstract
In this paper the results of the investigation of Si-Crx resistive cermet films, which are promising for the development of broadband microbolometers of the microwave range, are presented. A model of the conductivity of cermet films based on the theory of transport in granular metals and diluted semiconductors is proposed.



Structure of electron eigenfunctions in the quantum theory of axial channeling
Abstract
The transverse motion of fast charged particles within a crystal in the continuous potential field of atomic chains may be quantized. In the present study, the eigenfunctions of the discrete spectrum of the transverse motion of an electron in the field of a single atomic chain or a pair of parallel chains are determined (with [110] chains in a silicon crystal used as an example). The differences between eigenfunctions in the cases corresponding to regular and chaotic motion within the classical limit are demonstrated.



Calculation of the angular distribution of reflected ions for the case of oblique incidence on the target surface
Abstract
The angular distributions of reflected medium-energy ions are numerically calculated for the case of oblique incidence on the target surface. Calculations are performed by solving the one-velocity transport equation involving the scattering cross section of a truncated Coulomb potential. The results obtained via the method of discrete streams are a generalization of well-known Chandrasekhar data corresponding to simpler scattering cross sections. Theoretical angular distributions are compared with those obtained experimentally.


